Bis{μ-4-chloro-N′-[(E)-1-(5-chloro-2-oxidophen­yl)ethyl­idene]benzohydrazidato}bis­[pyridine­copper(II)]

The crystal structure of the title complex, [Cu(2)(C(15)H(10)Cl(2)N(2)O(2))(2)(C(5)H(5)N)(2)], features centrosymmetric dimers. The Cu(II) ion is penta­coordinated in a quadratic pyramidal mode. The quadratic plane is formed by the O,O′,N-tridentate ligand and a pyridine mol­ecule. The fifth coordin...

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Detalles Bibliográficos
Autor principal: Chang, Jian-Guo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238770/
https://www.ncbi.nlm.nih.gov/pubmed/22199647
http://dx.doi.org/10.1107/S1600536811050720
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author Chang, Jian-Guo
author_facet Chang, Jian-Guo
author_sort Chang, Jian-Guo
collection PubMed
description The crystal structure of the title complex, [Cu(2)(C(15)H(10)Cl(2)N(2)O(2))(2)(C(5)H(5)N)(2)], features centrosymmetric dimers. The Cu(II) ion is penta­coordinated in a quadratic pyramidal mode. The quadratic plane is formed by the O,O′,N-tridentate ligand and a pyridine mol­ecule. The fifth coordination site is occupied by the O atom of another ligand showing a significantly longer Cu—O bond.
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spelling pubmed-32387702011-12-23 Bis{μ-4-chloro-N′-[(E)-1-(5-chloro-2-oxidophen­yl)ethyl­idene]benzohydrazidato}bis­[pyridine­copper(II)] Chang, Jian-Guo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title complex, [Cu(2)(C(15)H(10)Cl(2)N(2)O(2))(2)(C(5)H(5)N)(2)], features centrosymmetric dimers. The Cu(II) ion is penta­coordinated in a quadratic pyramidal mode. The quadratic plane is formed by the O,O′,N-tridentate ligand and a pyridine mol­ecule. The fifth coordination site is occupied by the O atom of another ligand showing a significantly longer Cu—O bond. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238770/ /pubmed/22199647 http://dx.doi.org/10.1107/S1600536811050720 Text en © Jian-Guo Chang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chang, Jian-Guo
Bis{μ-4-chloro-N′-[(E)-1-(5-chloro-2-oxidophen­yl)ethyl­idene]benzohydrazidato}bis­[pyridine­copper(II)]
title Bis{μ-4-chloro-N′-[(E)-1-(5-chloro-2-oxidophen­yl)ethyl­idene]benzohydrazidato}bis­[pyridine­copper(II)]
title_full Bis{μ-4-chloro-N′-[(E)-1-(5-chloro-2-oxidophen­yl)ethyl­idene]benzohydrazidato}bis­[pyridine­copper(II)]
title_fullStr Bis{μ-4-chloro-N′-[(E)-1-(5-chloro-2-oxidophen­yl)ethyl­idene]benzohydrazidato}bis­[pyridine­copper(II)]
title_full_unstemmed Bis{μ-4-chloro-N′-[(E)-1-(5-chloro-2-oxidophen­yl)ethyl­idene]benzohydrazidato}bis­[pyridine­copper(II)]
title_short Bis{μ-4-chloro-N′-[(E)-1-(5-chloro-2-oxidophen­yl)ethyl­idene]benzohydrazidato}bis­[pyridine­copper(II)]
title_sort bis{μ-4-chloro-n′-[(e)-1-(5-chloro-2-oxidophen­yl)ethyl­idene]benzohydrazidato}bis­[pyridine­copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238770/
https://www.ncbi.nlm.nih.gov/pubmed/22199647
http://dx.doi.org/10.1107/S1600536811050720
work_keys_str_mv AT changjianguo bism4chlorone15chloro2oxidophenylethylidenebenzohydrazidatobispyridinecopperii

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