N,N,N′,N′-Tetra­methyl-N,N′-dipropyl­ethane-1,2-diaminium tetra­chlorido­cobaltate(II)

The crystal structure of the title compound, (C(12)H(30)N(2))[CoCl(4)], is composed of discrete (C(12)H(30)N(2))(2+) cations and [CoCl(4)](2−) anions. The asymmetric unit contains a half-cation and a half-anion. The atoms of the cation occupy general positions about an inversion centre, which is loc...

Descripción completa

Detalles Bibliográficos
Autores principales: Närhi, Sari M., Kostamo, Jatta, Asikkala, Janne, Oilunkaniemi, Raija, Laitinen, Risto S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238771/
https://www.ncbi.nlm.nih.gov/pubmed/22199648
http://dx.doi.org/10.1107/S1600536811050744
_version_ 1782219054835040256
author Närhi, Sari M.
Kostamo, Jatta
Asikkala, Janne
Oilunkaniemi, Raija
Laitinen, Risto S.
author_facet Närhi, Sari M.
Kostamo, Jatta
Asikkala, Janne
Oilunkaniemi, Raija
Laitinen, Risto S.
author_sort Närhi, Sari M.
collection PubMed
description The crystal structure of the title compound, (C(12)H(30)N(2))[CoCl(4)], is composed of discrete (C(12)H(30)N(2))(2+) cations and [CoCl(4)](2−) anions. The asymmetric unit contains a half-cation and a half-anion. The atoms of the cation occupy general positions about an inversion centre, which is located at the midpoint of the central C—C bond. The Co atoms lie on a twofold rotation axis. The slightly distorted tetra­hedral coordination environment around the metal atom consists of two Cl atoms and their symmetry-related pairs.
format Online
Article
Text
id pubmed-3238771
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32387712011-12-23 N,N,N′,N′-Tetra­methyl-N,N′-dipropyl­ethane-1,2-diaminium tetra­chlorido­cobaltate(II) Närhi, Sari M. Kostamo, Jatta Asikkala, Janne Oilunkaniemi, Raija Laitinen, Risto S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, (C(12)H(30)N(2))[CoCl(4)], is composed of discrete (C(12)H(30)N(2))(2+) cations and [CoCl(4)](2−) anions. The asymmetric unit contains a half-cation and a half-anion. The atoms of the cation occupy general positions about an inversion centre, which is located at the midpoint of the central C—C bond. The Co atoms lie on a twofold rotation axis. The slightly distorted tetra­hedral coordination environment around the metal atom consists of two Cl atoms and their symmetry-related pairs. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238771/ /pubmed/22199648 http://dx.doi.org/10.1107/S1600536811050744 Text en © Närhi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Närhi, Sari M.
Kostamo, Jatta
Asikkala, Janne
Oilunkaniemi, Raija
Laitinen, Risto S.
N,N,N′,N′-Tetra­methyl-N,N′-dipropyl­ethane-1,2-diaminium tetra­chlorido­cobaltate(II)
title N,N,N′,N′-Tetra­methyl-N,N′-dipropyl­ethane-1,2-diaminium tetra­chlorido­cobaltate(II)
title_full N,N,N′,N′-Tetra­methyl-N,N′-dipropyl­ethane-1,2-diaminium tetra­chlorido­cobaltate(II)
title_fullStr N,N,N′,N′-Tetra­methyl-N,N′-dipropyl­ethane-1,2-diaminium tetra­chlorido­cobaltate(II)
title_full_unstemmed N,N,N′,N′-Tetra­methyl-N,N′-dipropyl­ethane-1,2-diaminium tetra­chlorido­cobaltate(II)
title_short N,N,N′,N′-Tetra­methyl-N,N′-dipropyl­ethane-1,2-diaminium tetra­chlorido­cobaltate(II)
title_sort n,n,n′,n′-tetra­methyl-n,n′-dipropyl­ethane-1,2-diaminium tetra­chlorido­cobaltate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238771/
https://www.ncbi.nlm.nih.gov/pubmed/22199648
http://dx.doi.org/10.1107/S1600536811050744
work_keys_str_mv AT narhisarim nnnntetramethylnndipropylethane12diaminiumtetrachloridocobaltateii
AT kostamojatta nnnntetramethylnndipropylethane12diaminiumtetrachloridocobaltateii
AT asikkalajanne nnnntetramethylnndipropylethane12diaminiumtetrachloridocobaltateii
AT oilunkaniemiraija nnnntetramethylnndipropylethane12diaminiumtetrachloridocobaltateii
AT laitinenristos nnnntetramethylnndipropylethane12diaminiumtetrachloridocobaltateii

Ejemplares similares