catena-Poly[[copper(II)-bis­[μ-bis­(pyridin-3-yl)methanone-κ(2) N:N′]] bis­(tetra­fluorido­borate)]

In the title complex, {[Cu(C(11)H(8)N(2)O)(2)](BF(4))(2)}(n), the Cu(II) ion is situated on an inversion centre and adopts an N(4)F(2) octa­hedral coordination geometry with four N atoms from four different bis­(pyridin-3-yl)methanone ligands at the equatorial sites and two independent tetra­fluorid...

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Detalles Bibliográficos
Autor principal: Liu, Bin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238772/
https://www.ncbi.nlm.nih.gov/pubmed/22199649
http://dx.doi.org/10.1107/S1600536811050628
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author Liu, Bin
author_facet Liu, Bin
author_sort Liu, Bin
collection PubMed
description In the title complex, {[Cu(C(11)H(8)N(2)O)(2)](BF(4))(2)}(n), the Cu(II) ion is situated on an inversion centre and adopts an N(4)F(2) octa­hedral coordination geometry with four N atoms from four different bis­(pyridin-3-yl)methanone ligands at the equatorial sites and two independent tetra­fluoridoborate anions weakly bonded at the axial sites via two F atoms [Cu⋯F = 2.613 (3) Å]. Chains with the bridging ligands are formed along the a axis. C—H⋯F inter­actions stabilize the structure. C—O⋯π inter­actions also occur.
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spelling pubmed-32387722011-12-23 catena-Poly[[copper(II)-bis­[μ-bis­(pyridin-3-yl)methanone-κ(2) N:N′]] bis­(tetra­fluorido­borate)] Liu, Bin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {[Cu(C(11)H(8)N(2)O)(2)](BF(4))(2)}(n), the Cu(II) ion is situated on an inversion centre and adopts an N(4)F(2) octa­hedral coordination geometry with four N atoms from four different bis­(pyridin-3-yl)methanone ligands at the equatorial sites and two independent tetra­fluoridoborate anions weakly bonded at the axial sites via two F atoms [Cu⋯F = 2.613 (3) Å]. Chains with the bridging ligands are formed along the a axis. C—H⋯F inter­actions stabilize the structure. C—O⋯π inter­actions also occur. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238772/ /pubmed/22199649 http://dx.doi.org/10.1107/S1600536811050628 Text en © Bin Liu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Bin
catena-Poly[[copper(II)-bis­[μ-bis­(pyridin-3-yl)methanone-κ(2) N:N′]] bis­(tetra­fluorido­borate)]
title catena-Poly[[copper(II)-bis­[μ-bis­(pyridin-3-yl)methanone-κ(2) N:N′]] bis­(tetra­fluorido­borate)]
title_full catena-Poly[[copper(II)-bis­[μ-bis­(pyridin-3-yl)methanone-κ(2) N:N′]] bis­(tetra­fluorido­borate)]
title_fullStr catena-Poly[[copper(II)-bis­[μ-bis­(pyridin-3-yl)methanone-κ(2) N:N′]] bis­(tetra­fluorido­borate)]
title_full_unstemmed catena-Poly[[copper(II)-bis­[μ-bis­(pyridin-3-yl)methanone-κ(2) N:N′]] bis­(tetra­fluorido­borate)]
title_short catena-Poly[[copper(II)-bis­[μ-bis­(pyridin-3-yl)methanone-κ(2) N:N′]] bis­(tetra­fluorido­borate)]
title_sort catena-poly[[copper(ii)-bis­[μ-bis­(pyridin-3-yl)methanone-κ(2) n:n′]] bis­(tetra­fluorido­borate)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238772/
https://www.ncbi.nlm.nih.gov/pubmed/22199649
http://dx.doi.org/10.1107/S1600536811050628
work_keys_str_mv AT liubin catenapolycopperiibismbispyridin3ylmethanonek2nnbistetrafluoridoborate

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