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Dichloridobis{2-[(dimethyl­amino)­meth­yl]phen­yl}bis­{2-[(dimethyl­aza­nium­yl)meth­yl]phen­yl}di-μ-hydroxido-di-μ(3)-oxido-tetra­phenyl­tetra­tin(IV) dichloride deuterochloro­form deca­solvate

The ladder-like structure of the tetranuclear title compound, [Sn(4)(C(6)H(5))(4)Cl(2)O(2)(OH)(2)(C(9)H(13)N)(2)(C(9)H(12)N)(2)]Cl(2)·10CDCl(3), consists of two five- and two six-coordinated Sn(IV) atoms bridged by oxide or hydroxide groups. The chelating ligands reveal rather strong Sn—N bonds [2.5...

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Detalles Bibliográficos
Autores principales: Turek, Jan, Padělková, Zdeňka
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238773/
https://www.ncbi.nlm.nih.gov/pubmed/22199650
http://dx.doi.org/10.1107/S1600536811048872
Descripción
Sumario:The ladder-like structure of the tetranuclear title compound, [Sn(4)(C(6)H(5))(4)Cl(2)O(2)(OH)(2)(C(9)H(13)N)(2)(C(9)H(12)N)(2)]Cl(2)·10CDCl(3), consists of two five- and two six-coordinated Sn(IV) atoms bridged by oxide or hydroxide groups. The chelating ligands reveal rather strong Sn—N bonds [2.517 (4) Å], but the protonated dimethylamino groups in the periphery of the complex show no interaction with the metal atoms. The complex cation is located on an inversion centre. The chloride anion is linked to the complex mol­ecule by strong intra­molecular O—H⋯Cl and N—H⋯Cl hydrogen bonds. Five independent deuterochloroform accompany the complex, two of them are disordered [occupancy ratios 0.63 (2):0.27 (2) and 0.60 (2):0.40 (2)].