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Dichloridobis{2-[(dimethylamino)methyl]phenyl}bis{2-[(dimethylazaniumyl)methyl]phenyl}di-μ-hydroxido-di-μ(3)-oxido-tetraphenyltetratin(IV) dichloride deuterochloroform decasolvate
The ladder-like structure of the tetranuclear title compound, [Sn(4)(C(6)H(5))(4)Cl(2)O(2)(OH)(2)(C(9)H(13)N)(2)(C(9)H(12)N)(2)]Cl(2)·10CDCl(3), consists of two five- and two six-coordinated Sn(IV) atoms bridged by oxide or hydroxide groups. The chelating ligands reveal rather strong Sn—N bonds [2.5...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238773/ https://www.ncbi.nlm.nih.gov/pubmed/22199650 http://dx.doi.org/10.1107/S1600536811048872 |
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author | Turek, Jan Padělková, Zdeňka |
author_facet | Turek, Jan Padělková, Zdeňka |
author_sort | Turek, Jan |
collection | PubMed |
description | The ladder-like structure of the tetranuclear title compound, [Sn(4)(C(6)H(5))(4)Cl(2)O(2)(OH)(2)(C(9)H(13)N)(2)(C(9)H(12)N)(2)]Cl(2)·10CDCl(3), consists of two five- and two six-coordinated Sn(IV) atoms bridged by oxide or hydroxide groups. The chelating ligands reveal rather strong Sn—N bonds [2.517 (4) Å], but the protonated dimethylamino groups in the periphery of the complex show no interaction with the metal atoms. The complex cation is located on an inversion centre. The chloride anion is linked to the complex molecule by strong intramolecular O—H⋯Cl and N—H⋯Cl hydrogen bonds. Five independent deuterochloroform accompany the complex, two of them are disordered [occupancy ratios 0.63 (2):0.27 (2) and 0.60 (2):0.40 (2)]. |
format | Online Article Text |
id | pubmed-3238773 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32387732011-12-23 Dichloridobis{2-[(dimethylamino)methyl]phenyl}bis{2-[(dimethylazaniumyl)methyl]phenyl}di-μ-hydroxido-di-μ(3)-oxido-tetraphenyltetratin(IV) dichloride deuterochloroform decasolvate Turek, Jan Padělková, Zdeňka Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The ladder-like structure of the tetranuclear title compound, [Sn(4)(C(6)H(5))(4)Cl(2)O(2)(OH)(2)(C(9)H(13)N)(2)(C(9)H(12)N)(2)]Cl(2)·10CDCl(3), consists of two five- and two six-coordinated Sn(IV) atoms bridged by oxide or hydroxide groups. The chelating ligands reveal rather strong Sn—N bonds [2.517 (4) Å], but the protonated dimethylamino groups in the periphery of the complex show no interaction with the metal atoms. The complex cation is located on an inversion centre. The chloride anion is linked to the complex molecule by strong intramolecular O—H⋯Cl and N—H⋯Cl hydrogen bonds. Five independent deuterochloroform accompany the complex, two of them are disordered [occupancy ratios 0.63 (2):0.27 (2) and 0.60 (2):0.40 (2)]. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238773/ /pubmed/22199650 http://dx.doi.org/10.1107/S1600536811048872 Text en © Turek and Padělková 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Turek, Jan Padělková, Zdeňka Dichloridobis{2-[(dimethylamino)methyl]phenyl}bis{2-[(dimethylazaniumyl)methyl]phenyl}di-μ-hydroxido-di-μ(3)-oxido-tetraphenyltetratin(IV) dichloride deuterochloroform decasolvate |
title | Dichloridobis{2-[(dimethylamino)methyl]phenyl}bis{2-[(dimethylazaniumyl)methyl]phenyl}di-μ-hydroxido-di-μ(3)-oxido-tetraphenyltetratin(IV) dichloride deuterochloroform decasolvate |
title_full | Dichloridobis{2-[(dimethylamino)methyl]phenyl}bis{2-[(dimethylazaniumyl)methyl]phenyl}di-μ-hydroxido-di-μ(3)-oxido-tetraphenyltetratin(IV) dichloride deuterochloroform decasolvate |
title_fullStr | Dichloridobis{2-[(dimethylamino)methyl]phenyl}bis{2-[(dimethylazaniumyl)methyl]phenyl}di-μ-hydroxido-di-μ(3)-oxido-tetraphenyltetratin(IV) dichloride deuterochloroform decasolvate |
title_full_unstemmed | Dichloridobis{2-[(dimethylamino)methyl]phenyl}bis{2-[(dimethylazaniumyl)methyl]phenyl}di-μ-hydroxido-di-μ(3)-oxido-tetraphenyltetratin(IV) dichloride deuterochloroform decasolvate |
title_short | Dichloridobis{2-[(dimethylamino)methyl]phenyl}bis{2-[(dimethylazaniumyl)methyl]phenyl}di-μ-hydroxido-di-μ(3)-oxido-tetraphenyltetratin(IV) dichloride deuterochloroform decasolvate |
title_sort | dichloridobis{2-[(dimethylamino)methyl]phenyl}bis{2-[(dimethylazaniumyl)methyl]phenyl}di-μ-hydroxido-di-μ(3)-oxido-tetraphenyltetratin(iv) dichloride deuterochloroform decasolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238773/ https://www.ncbi.nlm.nih.gov/pubmed/22199650 http://dx.doi.org/10.1107/S1600536811048872 |
work_keys_str_mv | AT turekjan dichloridobis2dimethylaminomethylphenylbis2dimethylazaniumylmethylphenyldimhydroxidodim3oxidotetraphenyltetratinivdichloridedeuterochloroformdecasolvate AT padelkovazdenka dichloridobis2dimethylaminomethylphenylbis2dimethylazaniumylmethylphenyldimhydroxidodim3oxidotetraphenyltetratinivdichloridedeuterochloroformdecasolvate |