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Dichloridobis{2-[(dimethyl­amino)­meth­yl]phen­yl}bis­{2-[(dimethyl­aza­nium­yl)meth­yl]phen­yl}di-μ-hydroxido-di-μ(3)-oxido-tetra­phenyl­tetra­tin(IV) dichloride deuterochloro­form deca­solvate

The ladder-like structure of the tetranuclear title compound, [Sn(4)(C(6)H(5))(4)Cl(2)O(2)(OH)(2)(C(9)H(13)N)(2)(C(9)H(12)N)(2)]Cl(2)·10CDCl(3), consists of two five- and two six-coordinated Sn(IV) atoms bridged by oxide or hydroxide groups. The chelating ligands reveal rather strong Sn—N bonds [2.5...

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Detalles Bibliográficos
Autores principales: Turek, Jan, Padělková, Zdeňka
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238773/
https://www.ncbi.nlm.nih.gov/pubmed/22199650
http://dx.doi.org/10.1107/S1600536811048872
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author Turek, Jan
Padělková, Zdeňka
author_facet Turek, Jan
Padělková, Zdeňka
author_sort Turek, Jan
collection PubMed
description The ladder-like structure of the tetranuclear title compound, [Sn(4)(C(6)H(5))(4)Cl(2)O(2)(OH)(2)(C(9)H(13)N)(2)(C(9)H(12)N)(2)]Cl(2)·10CDCl(3), consists of two five- and two six-coordinated Sn(IV) atoms bridged by oxide or hydroxide groups. The chelating ligands reveal rather strong Sn—N bonds [2.517 (4) Å], but the protonated dimethylamino groups in the periphery of the complex show no interaction with the metal atoms. The complex cation is located on an inversion centre. The chloride anion is linked to the complex mol­ecule by strong intra­molecular O—H⋯Cl and N—H⋯Cl hydrogen bonds. Five independent deuterochloroform accompany the complex, two of them are disordered [occupancy ratios 0.63 (2):0.27 (2) and 0.60 (2):0.40 (2)].
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spelling pubmed-32387732011-12-23 Dichloridobis{2-[(dimethyl­amino)­meth­yl]phen­yl}bis­{2-[(dimethyl­aza­nium­yl)meth­yl]phen­yl}di-μ-hydroxido-di-μ(3)-oxido-tetra­phenyl­tetra­tin(IV) dichloride deuterochloro­form deca­solvate Turek, Jan Padělková, Zdeňka Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The ladder-like structure of the tetranuclear title compound, [Sn(4)(C(6)H(5))(4)Cl(2)O(2)(OH)(2)(C(9)H(13)N)(2)(C(9)H(12)N)(2)]Cl(2)·10CDCl(3), consists of two five- and two six-coordinated Sn(IV) atoms bridged by oxide or hydroxide groups. The chelating ligands reveal rather strong Sn—N bonds [2.517 (4) Å], but the protonated dimethylamino groups in the periphery of the complex show no interaction with the metal atoms. The complex cation is located on an inversion centre. The chloride anion is linked to the complex mol­ecule by strong intra­molecular O—H⋯Cl and N—H⋯Cl hydrogen bonds. Five independent deuterochloroform accompany the complex, two of them are disordered [occupancy ratios 0.63 (2):0.27 (2) and 0.60 (2):0.40 (2)]. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238773/ /pubmed/22199650 http://dx.doi.org/10.1107/S1600536811048872 Text en © Turek and Padělková 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Turek, Jan
Padělková, Zdeňka
Dichloridobis{2-[(dimethyl­amino)­meth­yl]phen­yl}bis­{2-[(dimethyl­aza­nium­yl)meth­yl]phen­yl}di-μ-hydroxido-di-μ(3)-oxido-tetra­phenyl­tetra­tin(IV) dichloride deuterochloro­form deca­solvate
title Dichloridobis{2-[(dimethyl­amino)­meth­yl]phen­yl}bis­{2-[(dimethyl­aza­nium­yl)meth­yl]phen­yl}di-μ-hydroxido-di-μ(3)-oxido-tetra­phenyl­tetra­tin(IV) dichloride deuterochloro­form deca­solvate
title_full Dichloridobis{2-[(dimethyl­amino)­meth­yl]phen­yl}bis­{2-[(dimethyl­aza­nium­yl)meth­yl]phen­yl}di-μ-hydroxido-di-μ(3)-oxido-tetra­phenyl­tetra­tin(IV) dichloride deuterochloro­form deca­solvate
title_fullStr Dichloridobis{2-[(dimethyl­amino)­meth­yl]phen­yl}bis­{2-[(dimethyl­aza­nium­yl)meth­yl]phen­yl}di-μ-hydroxido-di-μ(3)-oxido-tetra­phenyl­tetra­tin(IV) dichloride deuterochloro­form deca­solvate
title_full_unstemmed Dichloridobis{2-[(dimethyl­amino)­meth­yl]phen­yl}bis­{2-[(dimethyl­aza­nium­yl)meth­yl]phen­yl}di-μ-hydroxido-di-μ(3)-oxido-tetra­phenyl­tetra­tin(IV) dichloride deuterochloro­form deca­solvate
title_short Dichloridobis{2-[(dimethyl­amino)­meth­yl]phen­yl}bis­{2-[(dimethyl­aza­nium­yl)meth­yl]phen­yl}di-μ-hydroxido-di-μ(3)-oxido-tetra­phenyl­tetra­tin(IV) dichloride deuterochloro­form deca­solvate
title_sort dichloridobis{2-[(dimethyl­amino)­meth­yl]phen­yl}bis­{2-[(dimethyl­aza­nium­yl)meth­yl]phen­yl}di-μ-hydroxido-di-μ(3)-oxido-tetra­phenyl­tetra­tin(iv) dichloride deuterochloro­form deca­solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238773/
https://www.ncbi.nlm.nih.gov/pubmed/22199650
http://dx.doi.org/10.1107/S1600536811048872
work_keys_str_mv AT turekjan dichloridobis2dimethylaminomethylphenylbis2dimethylazaniumylmethylphenyldimhydroxidodim3oxidotetraphenyltetratinivdichloridedeuterochloroformdecasolvate
AT padelkovazdenka dichloridobis2dimethylaminomethylphenylbis2dimethylazaniumylmethylphenyldimhydroxidodim3oxidotetraphenyltetratinivdichloridedeuterochloroformdecasolvate