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Tetra-μ-acetato-κ(8) O:O′-bis{[2,2-dimethyl-N-(pyridin-2-yl)propanamide-κN (1)]copper(II)}(Cu—Cu)
The crystal structure of the title compound, [Cu(2)(C(2)H(3)O(2))(4)(C(10)H(14)N(2)O)(2)], reveals a dinuclear Cu(II) complex located about a center of inversion. The coordination environment of each Cu(II) cation is distorted octahedral, composed of four bridging acetate ligands, an apical pyridin...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238774/ https://www.ncbi.nlm.nih.gov/pubmed/22199651 http://dx.doi.org/10.1107/S1600536811050124 |
Sumario: | The crystal structure of the title compound, [Cu(2)(C(2)H(3)O(2))(4)(C(10)H(14)N(2)O)(2)], reveals a dinuclear Cu(II) complex located about a center of inversion. The coordination environment of each Cu(II) cation is distorted octahedral, composed of four bridging acetate ligands, an apical pyridine donor and is completed by a Cu—Cu bond. The amide H atom forms intramolecular hydrogen bonds to two carboxyl O atoms. In the crystal, weak intermolecular pyridine–amide C—H⋯O interactions are also present. |
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