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Tetra-μ-acetato-κ(8) O:O′-bis{[2,2-dimethyl-N-(pyridin-2-yl)propanamide-κN (1)]copper(II)}(Cu—Cu)
The crystal structure of the title compound, [Cu(2)(C(2)H(3)O(2))(4)(C(10)H(14)N(2)O)(2)], reveals a dinuclear Cu(II) complex located about a center of inversion. The coordination environment of each Cu(II) cation is distorted octahedral, composed of four bridging acetate ligands, an apical pyridin...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238774/ https://www.ncbi.nlm.nih.gov/pubmed/22199651 http://dx.doi.org/10.1107/S1600536811050124 |
| _version_ | 1782219055526051840 |
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| author | Asem, Samuel Buchanan, Robert M. Mashuta, Mark S. |
| author_facet | Asem, Samuel Buchanan, Robert M. Mashuta, Mark S. |
| author_sort | Asem, Samuel |
| collection | PubMed |
| description | The crystal structure of the title compound, [Cu(2)(C(2)H(3)O(2))(4)(C(10)H(14)N(2)O)(2)], reveals a dinuclear Cu(II) complex located about a center of inversion. The coordination environment of each Cu(II) cation is distorted octahedral, composed of four bridging acetate ligands, an apical pyridine donor and is completed by a Cu—Cu bond. The amide H atom forms intramolecular hydrogen bonds to two carboxyl O atoms. In the crystal, weak intermolecular pyridine–amide C—H⋯O interactions are also present. |
| format | Online Article Text |
| id | pubmed-3238774 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32387742011-12-23 Tetra-μ-acetato-κ(8) O:O′-bis{[2,2-dimethyl-N-(pyridin-2-yl)propanamide-κN (1)]copper(II)}(Cu—Cu) Asem, Samuel Buchanan, Robert M. Mashuta, Mark S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, [Cu(2)(C(2)H(3)O(2))(4)(C(10)H(14)N(2)O)(2)], reveals a dinuclear Cu(II) complex located about a center of inversion. The coordination environment of each Cu(II) cation is distorted octahedral, composed of four bridging acetate ligands, an apical pyridine donor and is completed by a Cu—Cu bond. The amide H atom forms intramolecular hydrogen bonds to two carboxyl O atoms. In the crystal, weak intermolecular pyridine–amide C—H⋯O interactions are also present. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238774/ /pubmed/22199651 http://dx.doi.org/10.1107/S1600536811050124 Text en © Asem et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Asem, Samuel Buchanan, Robert M. Mashuta, Mark S. Tetra-μ-acetato-κ(8) O:O′-bis{[2,2-dimethyl-N-(pyridin-2-yl)propanamide-κN (1)]copper(II)}(Cu—Cu) |
| title | Tetra-μ-acetato-κ(8)
O:O′-bis{[2,2-dimethyl-N-(pyridin-2-yl)propanamide-κN
(1)]copper(II)}(Cu—Cu) |
| title_full | Tetra-μ-acetato-κ(8)
O:O′-bis{[2,2-dimethyl-N-(pyridin-2-yl)propanamide-κN
(1)]copper(II)}(Cu—Cu) |
| title_fullStr | Tetra-μ-acetato-κ(8)
O:O′-bis{[2,2-dimethyl-N-(pyridin-2-yl)propanamide-κN
(1)]copper(II)}(Cu—Cu) |
| title_full_unstemmed | Tetra-μ-acetato-κ(8)
O:O′-bis{[2,2-dimethyl-N-(pyridin-2-yl)propanamide-κN
(1)]copper(II)}(Cu—Cu) |
| title_short | Tetra-μ-acetato-κ(8)
O:O′-bis{[2,2-dimethyl-N-(pyridin-2-yl)propanamide-κN
(1)]copper(II)}(Cu—Cu) |
| title_sort | tetra-μ-acetato-κ(8)
o:o′-bis{[2,2-dimethyl-n-(pyridin-2-yl)propanamide-κn
(1)]copper(ii)}(cu—cu) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238774/ https://www.ncbi.nlm.nih.gov/pubmed/22199651 http://dx.doi.org/10.1107/S1600536811050124 |
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