Dichloridobis(4-methyl-3,5-diphenyl-1H-pyrazole-κN (2))copper(II)

The asymmetric unit of the title compound, [CuCl(2)(C(16)H(14)N(2))(2)], comprises half of the complex. The Cu(II) atom lies on a crystallographic twofold rotation axis and shows a significantly distorted tetra­hedral coordination geometry. The dihedral angle between the phenyl rings is 74.3 (2)°. T...

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Detalles Bibliográficos
Autores principales: Hossaini Sadr, Moayad, Soltani, Behzad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238775/
https://www.ncbi.nlm.nih.gov/pubmed/22199652
http://dx.doi.org/10.1107/S1600536811050690
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author Hossaini Sadr, Moayad
Soltani, Behzad
author_facet Hossaini Sadr, Moayad
Soltani, Behzad
author_sort Hossaini Sadr, Moayad
collection PubMed
description The asymmetric unit of the title compound, [CuCl(2)(C(16)H(14)N(2))(2)], comprises half of the complex. The Cu(II) atom lies on a crystallographic twofold rotation axis and shows a significantly distorted tetra­hedral coordination geometry. The dihedral angle between the phenyl rings is 74.3 (2)°. The crystal structure is stabilized by inter­molecular π–π inter­actions [centroid–centroid distances = 3.635 (2)–3.803 (3) Å].
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spelling pubmed-32387752011-12-23 Dichloridobis(4-methyl-3,5-diphenyl-1H-pyrazole-κN (2))copper(II) Hossaini Sadr, Moayad Soltani, Behzad Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [CuCl(2)(C(16)H(14)N(2))(2)], comprises half of the complex. The Cu(II) atom lies on a crystallographic twofold rotation axis and shows a significantly distorted tetra­hedral coordination geometry. The dihedral angle between the phenyl rings is 74.3 (2)°. The crystal structure is stabilized by inter­molecular π–π inter­actions [centroid–centroid distances = 3.635 (2)–3.803 (3) Å]. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238775/ /pubmed/22199652 http://dx.doi.org/10.1107/S1600536811050690 Text en © Hossaini Sadr and Soltani 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hossaini Sadr, Moayad
Soltani, Behzad
Dichloridobis(4-methyl-3,5-diphenyl-1H-pyrazole-κN (2))copper(II)
title Dichloridobis(4-methyl-3,5-diphenyl-1H-pyrazole-κN (2))copper(II)
title_full Dichloridobis(4-methyl-3,5-diphenyl-1H-pyrazole-κN (2))copper(II)
title_fullStr Dichloridobis(4-methyl-3,5-diphenyl-1H-pyrazole-κN (2))copper(II)
title_full_unstemmed Dichloridobis(4-methyl-3,5-diphenyl-1H-pyrazole-κN (2))copper(II)
title_short Dichloridobis(4-methyl-3,5-diphenyl-1H-pyrazole-κN (2))copper(II)
title_sort dichloridobis(4-methyl-3,5-diphenyl-1h-pyrazole-κn (2))copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238775/
https://www.ncbi.nlm.nih.gov/pubmed/22199652
http://dx.doi.org/10.1107/S1600536811050690
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