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trans-Dichloridobis(4-phenyl­pyridine-κN)palladium(II)

The asymmetric unit of the title complex, [PdCl(2)(C(11)H(9)N)(2)], contains one half of a neutral Pd(II) complex, with the complete mol­ecule generated by the application of a twofold rotation axis; the N—Pd—N atoms lie on the axis. The Pd(II) ion has a trans-Cl(2)N(2) square-planar coordination ge...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238776/
https://www.ncbi.nlm.nih.gov/pubmed/22199653
http://dx.doi.org/10.1107/S160053681105063X
Descripción
Sumario:The asymmetric unit of the title complex, [PdCl(2)(C(11)H(9)N)(2)], contains one half of a neutral Pd(II) complex, with the complete mol­ecule generated by the application of a twofold rotation axis; the N—Pd—N atoms lie on the axis. The Pd(II) ion has a trans-Cl(2)N(2) square-planar coordination geometry defined by two N atoms from two 4-phenyl­pyridine ligands and two Cl(−) anions. In the refinement, the pyridine ring and the phenyl ring were found to be disordered over two sites with the site-occupancy factors being 0.53 (2) and 0.51 (1), respectively, for the major components.