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trans-Dichloridobis(4-phenylpyridine-κN)palladium(II)
The asymmetric unit of the title complex, [PdCl(2)(C(11)H(9)N)(2)], contains one half of a neutral Pd(II) complex, with the complete molecule generated by the application of a twofold rotation axis; the N—Pd—N atoms lie on the axis. The Pd(II) ion has a trans-Cl(2)N(2) square-planar coordination ge...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238776/ https://www.ncbi.nlm.nih.gov/pubmed/22199653 http://dx.doi.org/10.1107/S160053681105063X |
Sumario: | The asymmetric unit of the title complex, [PdCl(2)(C(11)H(9)N)(2)], contains one half of a neutral Pd(II) complex, with the complete molecule generated by the application of a twofold rotation axis; the N—Pd—N atoms lie on the axis. The Pd(II) ion has a trans-Cl(2)N(2) square-planar coordination geometry defined by two N atoms from two 4-phenylpyridine ligands and two Cl(−) anions. In the refinement, the pyridine ring and the phenyl ring were found to be disordered over two sites with the site-occupancy factors being 0.53 (2) and 0.51 (1), respectively, for the major components. |
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