trans-Dichloridobis(4-phenyl­pyridine-κN)palladium(II)

The asymmetric unit of the title complex, [PdCl(2)(C(11)H(9)N)(2)], contains one half of a neutral Pd(II) complex, with the complete mol­ecule generated by the application of a twofold rotation axis; the N—Pd—N atoms lie on the axis. The Pd(II) ion has a trans-Cl(2)N(2) square-planar coordination ge...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238776/
https://www.ncbi.nlm.nih.gov/pubmed/22199653
http://dx.doi.org/10.1107/S160053681105063X
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description The asymmetric unit of the title complex, [PdCl(2)(C(11)H(9)N)(2)], contains one half of a neutral Pd(II) complex, with the complete mol­ecule generated by the application of a twofold rotation axis; the N—Pd—N atoms lie on the axis. The Pd(II) ion has a trans-Cl(2)N(2) square-planar coordination geometry defined by two N atoms from two 4-phenyl­pyridine ligands and two Cl(−) anions. In the refinement, the pyridine ring and the phenyl ring were found to be disordered over two sites with the site-occupancy factors being 0.53 (2) and 0.51 (1), respectively, for the major components.
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spelling pubmed-32387762011-12-23 trans-Dichloridobis(4-phenyl­pyridine-κN)palladium(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [PdCl(2)(C(11)H(9)N)(2)], contains one half of a neutral Pd(II) complex, with the complete mol­ecule generated by the application of a twofold rotation axis; the N—Pd—N atoms lie on the axis. The Pd(II) ion has a trans-Cl(2)N(2) square-planar coordination geometry defined by two N atoms from two 4-phenyl­pyridine ligands and two Cl(−) anions. In the refinement, the pyridine ring and the phenyl ring were found to be disordered over two sites with the site-occupancy factors being 0.53 (2) and 0.51 (1), respectively, for the major components. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238776/ /pubmed/22199653 http://dx.doi.org/10.1107/S160053681105063X Text en © Kwang Ha 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
trans-Dichloridobis(4-phenyl­pyridine-κN)palladium(II)
title trans-Dichloridobis(4-phenyl­pyridine-κN)palladium(II)
title_full trans-Dichloridobis(4-phenyl­pyridine-κN)palladium(II)
title_fullStr trans-Dichloridobis(4-phenyl­pyridine-κN)palladium(II)
title_full_unstemmed trans-Dichloridobis(4-phenyl­pyridine-κN)palladium(II)
title_short trans-Dichloridobis(4-phenyl­pyridine-κN)palladium(II)
title_sort trans-dichloridobis(4-phenyl­pyridine-κn)palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238776/
https://www.ncbi.nlm.nih.gov/pubmed/22199653
http://dx.doi.org/10.1107/S160053681105063X
work_keys_str_mv AT hakwang transdichloridobis4phenylpyridineknpalladiumii

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