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Dibromido(2,3-di-2-pyridyl­pyrazine-κ(2) N (2),N (3))palladium(II)

The Pd(II) ion in the title complex, [PdBr(2)(C(14)H(10)N(4))], is four-coordinated in a slightly distorted square-planar environment by the two pyridine N atoms of the chelating 2,3-di-2-pyridyl­pyrazine (dpp) ligand and two bromide anions. The pyridine rings are considerably inclined to the least-...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238777/
https://www.ncbi.nlm.nih.gov/pubmed/22199654
http://dx.doi.org/10.1107/S1600536811050525
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description The Pd(II) ion in the title complex, [PdBr(2)(C(14)H(10)N(4))], is four-coordinated in a slightly distorted square-planar environment by the two pyridine N atoms of the chelating 2,3-di-2-pyridyl­pyrazine (dpp) ligand and two bromide anions. The pyridine rings are considerably inclined to the least-squares plane of the PdBr(2)N(2) unit [maximum deviation = 0.080 (2) Å], making dihedral angles of 64.9 (1) and 66.4 (1)°. The pyrazine ring is perpendicular to the unit plane, with a dihedral angle of 89.0 (1)°. In the crystal, the complex mol­ecules are stacked in columns along the a axis and connected by C—H⋯Br hydrogen bonds, forming a helical chain along the b axis.
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spelling pubmed-32387772011-12-23 Dibromido(2,3-di-2-pyridyl­pyrazine-κ(2) N (2),N (3))palladium(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pd(II) ion in the title complex, [PdBr(2)(C(14)H(10)N(4))], is four-coordinated in a slightly distorted square-planar environment by the two pyridine N atoms of the chelating 2,3-di-2-pyridyl­pyrazine (dpp) ligand and two bromide anions. The pyridine rings are considerably inclined to the least-squares plane of the PdBr(2)N(2) unit [maximum deviation = 0.080 (2) Å], making dihedral angles of 64.9 (1) and 66.4 (1)°. The pyrazine ring is perpendicular to the unit plane, with a dihedral angle of 89.0 (1)°. In the crystal, the complex mol­ecules are stacked in columns along the a axis and connected by C—H⋯Br hydrogen bonds, forming a helical chain along the b axis. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238777/ /pubmed/22199654 http://dx.doi.org/10.1107/S1600536811050525 Text en © Kwang Ha 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
Dibromido(2,3-di-2-pyridyl­pyrazine-κ(2) N (2),N (3))palladium(II)
title Dibromido(2,3-di-2-pyridyl­pyrazine-κ(2) N (2),N (3))palladium(II)
title_full Dibromido(2,3-di-2-pyridyl­pyrazine-κ(2) N (2),N (3))palladium(II)
title_fullStr Dibromido(2,3-di-2-pyridyl­pyrazine-κ(2) N (2),N (3))palladium(II)
title_full_unstemmed Dibromido(2,3-di-2-pyridyl­pyrazine-κ(2) N (2),N (3))palladium(II)
title_short Dibromido(2,3-di-2-pyridyl­pyrazine-κ(2) N (2),N (3))palladium(II)
title_sort dibromido(2,3-di-2-pyridyl­pyrazine-κ(2) n (2),n (3))palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238777/
https://www.ncbi.nlm.nih.gov/pubmed/22199654
http://dx.doi.org/10.1107/S1600536811050525
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