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Dibromido(2,3-di-2-pyridylpyrazine-κ(2) N (2),N (3))palladium(II)
The Pd(II) ion in the title complex, [PdBr(2)(C(14)H(10)N(4))], is four-coordinated in a slightly distorted square-planar environment by the two pyridine N atoms of the chelating 2,3-di-2-pyridylpyrazine (dpp) ligand and two bromide anions. The pyridine rings are considerably inclined to the least-...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238777/ https://www.ncbi.nlm.nih.gov/pubmed/22199654 http://dx.doi.org/10.1107/S1600536811050525 |
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author | Ha, Kwang |
author_facet | Ha, Kwang |
author_sort | Ha, Kwang |
collection | PubMed |
description | The Pd(II) ion in the title complex, [PdBr(2)(C(14)H(10)N(4))], is four-coordinated in a slightly distorted square-planar environment by the two pyridine N atoms of the chelating 2,3-di-2-pyridylpyrazine (dpp) ligand and two bromide anions. The pyridine rings are considerably inclined to the least-squares plane of the PdBr(2)N(2) unit [maximum deviation = 0.080 (2) Å], making dihedral angles of 64.9 (1) and 66.4 (1)°. The pyrazine ring is perpendicular to the unit plane, with a dihedral angle of 89.0 (1)°. In the crystal, the complex molecules are stacked in columns along the a axis and connected by C—H⋯Br hydrogen bonds, forming a helical chain along the b axis. |
format | Online Article Text |
id | pubmed-3238777 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32387772011-12-23 Dibromido(2,3-di-2-pyridylpyrazine-κ(2) N (2),N (3))palladium(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pd(II) ion in the title complex, [PdBr(2)(C(14)H(10)N(4))], is four-coordinated in a slightly distorted square-planar environment by the two pyridine N atoms of the chelating 2,3-di-2-pyridylpyrazine (dpp) ligand and two bromide anions. The pyridine rings are considerably inclined to the least-squares plane of the PdBr(2)N(2) unit [maximum deviation = 0.080 (2) Å], making dihedral angles of 64.9 (1) and 66.4 (1)°. The pyrazine ring is perpendicular to the unit plane, with a dihedral angle of 89.0 (1)°. In the crystal, the complex molecules are stacked in columns along the a axis and connected by C—H⋯Br hydrogen bonds, forming a helical chain along the b axis. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238777/ /pubmed/22199654 http://dx.doi.org/10.1107/S1600536811050525 Text en © Kwang Ha 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ha, Kwang Dibromido(2,3-di-2-pyridylpyrazine-κ(2) N (2),N (3))palladium(II) |
title | Dibromido(2,3-di-2-pyridylpyrazine-κ(2)
N
(2),N
(3))palladium(II) |
title_full | Dibromido(2,3-di-2-pyridylpyrazine-κ(2)
N
(2),N
(3))palladium(II) |
title_fullStr | Dibromido(2,3-di-2-pyridylpyrazine-κ(2)
N
(2),N
(3))palladium(II) |
title_full_unstemmed | Dibromido(2,3-di-2-pyridylpyrazine-κ(2)
N
(2),N
(3))palladium(II) |
title_short | Dibromido(2,3-di-2-pyridylpyrazine-κ(2)
N
(2),N
(3))palladium(II) |
title_sort | dibromido(2,3-di-2-pyridylpyrazine-κ(2)
n
(2),n
(3))palladium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238777/ https://www.ncbi.nlm.nih.gov/pubmed/22199654 http://dx.doi.org/10.1107/S1600536811050525 |
work_keys_str_mv | AT hakwang dibromido23di2pyridylpyrazinek2n2n3palladiumii |