1,3-Bis(2,4,6-trimethyl­phen­yl)-3H-imidazol-1-ium tetra­oxidorhenate(VII)

The title compound, (C(21)H(25)N(2))[ReO(4)], was formed as the unexpected product in an attempted synthesis of a rhenium(I)–N-heterocyclic carbene (NHC) complex. The compound has crystallographic mirror symmetry with both the cation and the tetrahedral anion located across a mirror plane. The catio...

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Autores principales: Landman, Marilé, van der Westhuizen, Belinda, Bezuidenhout, Daniela I., Liles, David C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238778/
https://www.ncbi.nlm.nih.gov/pubmed/22199655
http://dx.doi.org/10.1107/S1600536811050677
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author Landman, Marilé
van der Westhuizen, Belinda
Bezuidenhout, Daniela I.
Liles, David C.
author_facet Landman, Marilé
van der Westhuizen, Belinda
Bezuidenhout, Daniela I.
Liles, David C.
author_sort Landman, Marilé
collection PubMed
description The title compound, (C(21)H(25)N(2))[ReO(4)], was formed as the unexpected product in an attempted synthesis of a rhenium(I)–N-heterocyclic carbene (NHC) complex. The compound has crystallographic mirror symmetry with both the cation and the tetrahedral anion located across a mirror plane. The cation and anion are linked by a C—H⋯O hydrogen bond.
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spelling pubmed-32387782011-12-23 1,3-Bis(2,4,6-trimethyl­phen­yl)-3H-imidazol-1-ium tetra­oxidorhenate(VII) Landman, Marilé van der Westhuizen, Belinda Bezuidenhout, Daniela I. Liles, David C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(21)H(25)N(2))[ReO(4)], was formed as the unexpected product in an attempted synthesis of a rhenium(I)–N-heterocyclic carbene (NHC) complex. The compound has crystallographic mirror symmetry with both the cation and the tetrahedral anion located across a mirror plane. The cation and anion are linked by a C—H⋯O hydrogen bond. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238778/ /pubmed/22199655 http://dx.doi.org/10.1107/S1600536811050677 Text en © Landman et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Landman, Marilé
van der Westhuizen, Belinda
Bezuidenhout, Daniela I.
Liles, David C.
1,3-Bis(2,4,6-trimethyl­phen­yl)-3H-imidazol-1-ium tetra­oxidorhenate(VII)
title 1,3-Bis(2,4,6-trimethyl­phen­yl)-3H-imidazol-1-ium tetra­oxidorhenate(VII)
title_full 1,3-Bis(2,4,6-trimethyl­phen­yl)-3H-imidazol-1-ium tetra­oxidorhenate(VII)
title_fullStr 1,3-Bis(2,4,6-trimethyl­phen­yl)-3H-imidazol-1-ium tetra­oxidorhenate(VII)
title_full_unstemmed 1,3-Bis(2,4,6-trimethyl­phen­yl)-3H-imidazol-1-ium tetra­oxidorhenate(VII)
title_short 1,3-Bis(2,4,6-trimethyl­phen­yl)-3H-imidazol-1-ium tetra­oxidorhenate(VII)
title_sort 1,3-bis(2,4,6-trimethyl­phen­yl)-3h-imidazol-1-ium tetra­oxidorhenate(vii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238778/
https://www.ncbi.nlm.nih.gov/pubmed/22199655
http://dx.doi.org/10.1107/S1600536811050677
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