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Poly[[aqua(μ(5)-3,4,5,6-tetracarboxycyclohexane-1,2-dicarboxylato)strontium] monohydrate]
In the title compound, {[Sr(C(12)H(10)O(12))(H(2)O)]·H(2)O}(n), the Sr(II) ion is coordinated by six O atoms of five symmetry-related 3,4,5,6-tetracarboxycyclohexane-1,2-dicarboxylate ligands and one water molecule in a slightly distorted monocapped trigonal–prismatic environment. The ligands...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238780/ https://www.ncbi.nlm.nih.gov/pubmed/22199657 http://dx.doi.org/10.1107/S1600536811050811 |
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author | Cheng, Pei-Chi Zhan, Jun-Xiang Wu, Cheng-You Lin, Chia-Her |
author_facet | Cheng, Pei-Chi Zhan, Jun-Xiang Wu, Cheng-You Lin, Chia-Her |
author_sort | Cheng, Pei-Chi |
collection | PubMed |
description | In the title compound, {[Sr(C(12)H(10)O(12))(H(2)O)]·H(2)O}(n), the Sr(II) ion is coordinated by six O atoms of five symmetry-related 3,4,5,6-tetracarboxycyclohexane-1,2-dicarboxylate ligands and one water molecule in a slightly distorted monocapped trigonal–prismatic environment. The ligands bridge the Sr(II) ions, forming a two-dimensional structure. In the crystal, O—H⋯O hydrogen bonds further connect the structure into a three-dimensional network. The H atoms of two of the carboxyl groups were refined as half-occupancy. |
format | Online Article Text |
id | pubmed-3238780 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32387802011-12-23 Poly[[aqua(μ(5)-3,4,5,6-tetracarboxycyclohexane-1,2-dicarboxylato)strontium] monohydrate] Cheng, Pei-Chi Zhan, Jun-Xiang Wu, Cheng-You Lin, Chia-Her Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Sr(C(12)H(10)O(12))(H(2)O)]·H(2)O}(n), the Sr(II) ion is coordinated by six O atoms of five symmetry-related 3,4,5,6-tetracarboxycyclohexane-1,2-dicarboxylate ligands and one water molecule in a slightly distorted monocapped trigonal–prismatic environment. The ligands bridge the Sr(II) ions, forming a two-dimensional structure. In the crystal, O—H⋯O hydrogen bonds further connect the structure into a three-dimensional network. The H atoms of two of the carboxyl groups were refined as half-occupancy. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238780/ /pubmed/22199657 http://dx.doi.org/10.1107/S1600536811050811 Text en © Cheng et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Cheng, Pei-Chi Zhan, Jun-Xiang Wu, Cheng-You Lin, Chia-Her Poly[[aqua(μ(5)-3,4,5,6-tetracarboxycyclohexane-1,2-dicarboxylato)strontium] monohydrate] |
title | Poly[[aqua(μ(5)-3,4,5,6-tetracarboxycyclohexane-1,2-dicarboxylato)strontium] monohydrate] |
title_full | Poly[[aqua(μ(5)-3,4,5,6-tetracarboxycyclohexane-1,2-dicarboxylato)strontium] monohydrate] |
title_fullStr | Poly[[aqua(μ(5)-3,4,5,6-tetracarboxycyclohexane-1,2-dicarboxylato)strontium] monohydrate] |
title_full_unstemmed | Poly[[aqua(μ(5)-3,4,5,6-tetracarboxycyclohexane-1,2-dicarboxylato)strontium] monohydrate] |
title_short | Poly[[aqua(μ(5)-3,4,5,6-tetracarboxycyclohexane-1,2-dicarboxylato)strontium] monohydrate] |
title_sort | poly[[aqua(μ(5)-3,4,5,6-tetracarboxycyclohexane-1,2-dicarboxylato)strontium] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238780/ https://www.ncbi.nlm.nih.gov/pubmed/22199657 http://dx.doi.org/10.1107/S1600536811050811 |
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