(meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra­aza­cyclo­tetra­deca­ne)nickel(II) bis­[O,O′-(1,2-phenyl­ene) dithio­phosphate]

In the crystal structure of the title compound, [Ni(C(16)H(36)N(4))](C(6)H(4)O(2)PS(2))(2), the Ni(II) cation is located on a center of inversion and is chelated by the folded tetra­amine macrocycle ligand in a slightly distorted NiN(4) square-planar geometry. Two symmetry-related O,O′-(1,2-phenyl­e...

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Detalles Bibliográficos
Autores principales: Zou, Li-Ke, Lu, Yan, Cheng, Jie, He, Xi-Yang, Xie, Bin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238782/
https://www.ncbi.nlm.nih.gov/pubmed/22199659
http://dx.doi.org/10.1107/S1600536811050951
Descripción
Sumario:In the crystal structure of the title compound, [Ni(C(16)H(36)N(4))](C(6)H(4)O(2)PS(2))(2), the Ni(II) cation is located on a center of inversion and is chelated by the folded tetra­amine macrocycle ligand in a slightly distorted NiN(4) square-planar geometry. Two symmetry-related O,O′-(1,2-phenyl­ene)dithio­phosphate anions are located on either side of the Ni(II) cation, with Ni⋯S of 3.9558 (5) Å, and link to the tetra­amine macrocycle ligand via N—H⋯S hydrogen bonding.

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