(meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra­aza­cyclo­tetra­deca­ne)nickel(II) bis­[O,O′-(1,2-phenyl­ene) dithio­phosphate]

In the crystal structure of the title compound, [Ni(C(16)H(36)N(4))](C(6)H(4)O(2)PS(2))(2), the Ni(II) cation is located on a center of inversion and is chelated by the folded tetra­amine macrocycle ligand in a slightly distorted NiN(4) square-planar geometry. Two symmetry-related O,O′-(1,2-phenyl­e...

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Detalles Bibliográficos
Autores principales: Zou, Li-Ke, Lu, Yan, Cheng, Jie, He, Xi-Yang, Xie, Bin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238782/
https://www.ncbi.nlm.nih.gov/pubmed/22199659
http://dx.doi.org/10.1107/S1600536811050951
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author Zou, Li-Ke
Lu, Yan
Cheng, Jie
He, Xi-Yang
Xie, Bin
author_facet Zou, Li-Ke
Lu, Yan
Cheng, Jie
He, Xi-Yang
Xie, Bin
author_sort Zou, Li-Ke
collection PubMed
description In the crystal structure of the title compound, [Ni(C(16)H(36)N(4))](C(6)H(4)O(2)PS(2))(2), the Ni(II) cation is located on a center of inversion and is chelated by the folded tetra­amine macrocycle ligand in a slightly distorted NiN(4) square-planar geometry. Two symmetry-related O,O′-(1,2-phenyl­ene)dithio­phosphate anions are located on either side of the Ni(II) cation, with Ni⋯S of 3.9558 (5) Å, and link to the tetra­amine macrocycle ligand via N—H⋯S hydrogen bonding.
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spelling pubmed-32387822011-12-23 (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra­aza­cyclo­tetra­deca­ne)nickel(II) bis­[O,O′-(1,2-phenyl­ene) dithio­phosphate] Zou, Li-Ke Lu, Yan Cheng, Jie He, Xi-Yang Xie, Bin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Ni(C(16)H(36)N(4))](C(6)H(4)O(2)PS(2))(2), the Ni(II) cation is located on a center of inversion and is chelated by the folded tetra­amine macrocycle ligand in a slightly distorted NiN(4) square-planar geometry. Two symmetry-related O,O′-(1,2-phenyl­ene)dithio­phosphate anions are located on either side of the Ni(II) cation, with Ni⋯S of 3.9558 (5) Å, and link to the tetra­amine macrocycle ligand via N—H⋯S hydrogen bonding. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238782/ /pubmed/22199659 http://dx.doi.org/10.1107/S1600536811050951 Text en © Zou et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zou, Li-Ke
Lu, Yan
Cheng, Jie
He, Xi-Yang
Xie, Bin
(meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra­aza­cyclo­tetra­deca­ne)nickel(II) bis­[O,O′-(1,2-phenyl­ene) dithio­phosphate]
title (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra­aza­cyclo­tetra­deca­ne)nickel(II) bis­[O,O′-(1,2-phenyl­ene) dithio­phosphate]
title_full (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra­aza­cyclo­tetra­deca­ne)nickel(II) bis­[O,O′-(1,2-phenyl­ene) dithio­phosphate]
title_fullStr (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra­aza­cyclo­tetra­deca­ne)nickel(II) bis­[O,O′-(1,2-phenyl­ene) dithio­phosphate]
title_full_unstemmed (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra­aza­cyclo­tetra­deca­ne)nickel(II) bis­[O,O′-(1,2-phenyl­ene) dithio­phosphate]
title_short (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra­aza­cyclo­tetra­deca­ne)nickel(II) bis­[O,O′-(1,2-phenyl­ene) dithio­phosphate]
title_sort (meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetra­aza­cyclo­tetra­deca­ne)nickel(ii) bis­[o,o′-(1,2-phenyl­ene) dithio­phosphate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238782/
https://www.ncbi.nlm.nih.gov/pubmed/22199659
http://dx.doi.org/10.1107/S1600536811050951
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