Bis(chloro­acetato-κ(2) O,O′)bis­(2-fluoro­benzyl-κC (1))tin(IV)

In the title complex, [Sn(C(2)H(2)ClO(2))(2)(C(7)H(6)F)(2)], the Sn(IV) atom is located on a twofold rotation axis and forms a strongly distorted trans-octa­hedral geometry. The equatorial plane is defined by two chelating chloro­acetate ligands with asymmetrical Sn—O bond lengths, while the axial p...

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Detalles Bibliográficos
Autores principales: Deng, Aixia, Teng, Mouyong, Xie, Qian, Yan, Nana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238784/
https://www.ncbi.nlm.nih.gov/pubmed/22199661
http://dx.doi.org/10.1107/S1600536811051002
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author Deng, Aixia
Teng, Mouyong
Xie, Qian
Yan, Nana
author_facet Deng, Aixia
Teng, Mouyong
Xie, Qian
Yan, Nana
author_sort Deng, Aixia
collection PubMed
description In the title complex, [Sn(C(2)H(2)ClO(2))(2)(C(7)H(6)F)(2)], the Sn(IV) atom is located on a twofold rotation axis and forms a strongly distorted trans-octa­hedral geometry. The equatorial plane is defined by two chelating chloro­acetate ligands with asymmetrical Sn—O bond lengths, while the axial positions are occupied by the C atoms of two 2-fluoro­benzyl groups. In the crystal, infinite chains in the [010] direction are formed through inter­molecular Sn⋯O inter­actions [Sn⋯O separation = 3.682 (3) Å].
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spelling pubmed-32387842011-12-23 Bis(chloro­acetato-κ(2) O,O′)bis­(2-fluoro­benzyl-κC (1))tin(IV) Deng, Aixia Teng, Mouyong Xie, Qian Yan, Nana Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Sn(C(2)H(2)ClO(2))(2)(C(7)H(6)F)(2)], the Sn(IV) atom is located on a twofold rotation axis and forms a strongly distorted trans-octa­hedral geometry. The equatorial plane is defined by two chelating chloro­acetate ligands with asymmetrical Sn—O bond lengths, while the axial positions are occupied by the C atoms of two 2-fluoro­benzyl groups. In the crystal, infinite chains in the [010] direction are formed through inter­molecular Sn⋯O inter­actions [Sn⋯O separation = 3.682 (3) Å]. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238784/ /pubmed/22199661 http://dx.doi.org/10.1107/S1600536811051002 Text en © Deng et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Deng, Aixia
Teng, Mouyong
Xie, Qian
Yan, Nana
Bis(chloro­acetato-κ(2) O,O′)bis­(2-fluoro­benzyl-κC (1))tin(IV)
title Bis(chloro­acetato-κ(2) O,O′)bis­(2-fluoro­benzyl-κC (1))tin(IV)
title_full Bis(chloro­acetato-κ(2) O,O′)bis­(2-fluoro­benzyl-κC (1))tin(IV)
title_fullStr Bis(chloro­acetato-κ(2) O,O′)bis­(2-fluoro­benzyl-κC (1))tin(IV)
title_full_unstemmed Bis(chloro­acetato-κ(2) O,O′)bis­(2-fluoro­benzyl-κC (1))tin(IV)
title_short Bis(chloro­acetato-κ(2) O,O′)bis­(2-fluoro­benzyl-κC (1))tin(IV)
title_sort bis(chloro­acetato-κ(2) o,o′)bis­(2-fluoro­benzyl-κc (1))tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238784/
https://www.ncbi.nlm.nih.gov/pubmed/22199661
http://dx.doi.org/10.1107/S1600536811051002
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AT yannana bischloroacetatok2oobis2fluorobenzylkc1tiniv

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