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Bromidotetra­kis­(1H-2-ethyl-5-methyl­imidazole-κN (3))copper(II) bromide

The Cu(II) ion in the title compound, [CuBr(C(6)H(10)N(2))(4)]Br, is coordinated in a square-based-pyramidal geometry by the N atoms of four imidazole ligands and a bromide anion in the apical site. Both the Cu(II) and Br(−) atoms lie on a crystallographic fourfold axis. In the crystal, the [CuBr(C(...

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Autores principales: Godlewska, Sylwia, Baranowska, Katarzyna, Socha, Joanna, Dołęga, Anna
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238785/
https://www.ncbi.nlm.nih.gov/pubmed/22199662
http://dx.doi.org/10.1107/S1600536811051117
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author Godlewska, Sylwia
Baranowska, Katarzyna
Socha, Joanna
Dołęga, Anna
author_facet Godlewska, Sylwia
Baranowska, Katarzyna
Socha, Joanna
Dołęga, Anna
author_sort Godlewska, Sylwia
collection PubMed
description The Cu(II) ion in the title compound, [CuBr(C(6)H(10)N(2))(4)]Br, is coordinated in a square-based-pyramidal geometry by the N atoms of four imidazole ligands and a bromide anion in the apical site. Both the Cu(II) and Br(−) atoms lie on a crystallographic fourfold axis. In the crystal, the [CuBr(C(6)H(10)N(2))(4)](+) complex cations are linked to the uncoordinated Br(−) anions (site symmetry [Image: see text]) by N—H⋯Br hydrogen bonds, generating a three-dimensional network. The ethyl group of the imidazole ligand was modelled as disordered over two orientations with occupancies of 0.620 (8) and 0.380 (8).
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spelling pubmed-32387852011-12-23 Bromidotetra­kis­(1H-2-ethyl-5-methyl­imidazole-κN (3))copper(II) bromide Godlewska, Sylwia Baranowska, Katarzyna Socha, Joanna Dołęga, Anna Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cu(II) ion in the title compound, [CuBr(C(6)H(10)N(2))(4)]Br, is coordinated in a square-based-pyramidal geometry by the N atoms of four imidazole ligands and a bromide anion in the apical site. Both the Cu(II) and Br(−) atoms lie on a crystallographic fourfold axis. In the crystal, the [CuBr(C(6)H(10)N(2))(4)](+) complex cations are linked to the uncoordinated Br(−) anions (site symmetry [Image: see text]) by N—H⋯Br hydrogen bonds, generating a three-dimensional network. The ethyl group of the imidazole ligand was modelled as disordered over two orientations with occupancies of 0.620 (8) and 0.380 (8). International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238785/ /pubmed/22199662 http://dx.doi.org/10.1107/S1600536811051117 Text en © Godlewska et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Godlewska, Sylwia
Baranowska, Katarzyna
Socha, Joanna
Dołęga, Anna
Bromidotetra­kis­(1H-2-ethyl-5-methyl­imidazole-κN (3))copper(II) bromide
title Bromidotetra­kis­(1H-2-ethyl-5-methyl­imidazole-κN (3))copper(II) bromide
title_full Bromidotetra­kis­(1H-2-ethyl-5-methyl­imidazole-κN (3))copper(II) bromide
title_fullStr Bromidotetra­kis­(1H-2-ethyl-5-methyl­imidazole-κN (3))copper(II) bromide
title_full_unstemmed Bromidotetra­kis­(1H-2-ethyl-5-methyl­imidazole-κN (3))copper(II) bromide
title_short Bromidotetra­kis­(1H-2-ethyl-5-methyl­imidazole-κN (3))copper(II) bromide
title_sort bromidotetra­kis­(1h-2-ethyl-5-methyl­imidazole-κn (3))copper(ii) bromide
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238785/
https://www.ncbi.nlm.nih.gov/pubmed/22199662
http://dx.doi.org/10.1107/S1600536811051117
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