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Bromidotetrakis(1H-2-ethyl-5-methylimidazole-κN (3))copper(II) bromide
The Cu(II) ion in the title compound, [CuBr(C(6)H(10)N(2))(4)]Br, is coordinated in a square-based-pyramidal geometry by the N atoms of four imidazole ligands and a bromide anion in the apical site. Both the Cu(II) and Br(−) atoms lie on a crystallographic fourfold axis. In the crystal, the [CuBr(C(...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238785/ https://www.ncbi.nlm.nih.gov/pubmed/22199662 http://dx.doi.org/10.1107/S1600536811051117 |
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author | Godlewska, Sylwia Baranowska, Katarzyna Socha, Joanna Dołęga, Anna |
author_facet | Godlewska, Sylwia Baranowska, Katarzyna Socha, Joanna Dołęga, Anna |
author_sort | Godlewska, Sylwia |
collection | PubMed |
description | The Cu(II) ion in the title compound, [CuBr(C(6)H(10)N(2))(4)]Br, is coordinated in a square-based-pyramidal geometry by the N atoms of four imidazole ligands and a bromide anion in the apical site. Both the Cu(II) and Br(−) atoms lie on a crystallographic fourfold axis. In the crystal, the [CuBr(C(6)H(10)N(2))(4)](+) complex cations are linked to the uncoordinated Br(−) anions (site symmetry [Image: see text]) by N—H⋯Br hydrogen bonds, generating a three-dimensional network. The ethyl group of the imidazole ligand was modelled as disordered over two orientations with occupancies of 0.620 (8) and 0.380 (8). |
format | Online Article Text |
id | pubmed-3238785 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32387852011-12-23 Bromidotetrakis(1H-2-ethyl-5-methylimidazole-κN (3))copper(II) bromide Godlewska, Sylwia Baranowska, Katarzyna Socha, Joanna Dołęga, Anna Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cu(II) ion in the title compound, [CuBr(C(6)H(10)N(2))(4)]Br, is coordinated in a square-based-pyramidal geometry by the N atoms of four imidazole ligands and a bromide anion in the apical site. Both the Cu(II) and Br(−) atoms lie on a crystallographic fourfold axis. In the crystal, the [CuBr(C(6)H(10)N(2))(4)](+) complex cations are linked to the uncoordinated Br(−) anions (site symmetry [Image: see text]) by N—H⋯Br hydrogen bonds, generating a three-dimensional network. The ethyl group of the imidazole ligand was modelled as disordered over two orientations with occupancies of 0.620 (8) and 0.380 (8). International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238785/ /pubmed/22199662 http://dx.doi.org/10.1107/S1600536811051117 Text en © Godlewska et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Godlewska, Sylwia Baranowska, Katarzyna Socha, Joanna Dołęga, Anna Bromidotetrakis(1H-2-ethyl-5-methylimidazole-κN (3))copper(II) bromide |
title | Bromidotetrakis(1H-2-ethyl-5-methylimidazole-κN
(3))copper(II) bromide |
title_full | Bromidotetrakis(1H-2-ethyl-5-methylimidazole-κN
(3))copper(II) bromide |
title_fullStr | Bromidotetrakis(1H-2-ethyl-5-methylimidazole-κN
(3))copper(II) bromide |
title_full_unstemmed | Bromidotetrakis(1H-2-ethyl-5-methylimidazole-κN
(3))copper(II) bromide |
title_short | Bromidotetrakis(1H-2-ethyl-5-methylimidazole-κN
(3))copper(II) bromide |
title_sort | bromidotetrakis(1h-2-ethyl-5-methylimidazole-κn
(3))copper(ii) bromide |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238785/ https://www.ncbi.nlm.nih.gov/pubmed/22199662 http://dx.doi.org/10.1107/S1600536811051117 |
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