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Tetrakis[μ-3-(3-hydroxyphenyl)propenoato]bis{aqua(2,2′-bipyridine)[3-(3-hydroxyphenyl)propenoato]neodymium(III)} 2,2′-bipyridine disolvate dihydrate
The dinuclear title compound, [Nd(2)(C(9)H(7)O(3))(6)(C(10)H(8)N(2))(2)]·2C(10)H(8)N(2)·2H(2)O, was synthesized under hydrothermal conditions. The centrosymmetric complex consists of two nine-coordinated Nd(3+) cations, six 3-hydroxycinnamate anions and two chelating 2,2′-bipyridine molecules. T...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238786/ https://www.ncbi.nlm.nih.gov/pubmed/22199663 http://dx.doi.org/10.1107/S1600536811050707 |
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author | Guo, Jing-Ke Wen, Yi-Hang |
author_facet | Guo, Jing-Ke Wen, Yi-Hang |
author_sort | Guo, Jing-Ke |
collection | PubMed |
description | The dinuclear title compound, [Nd(2)(C(9)H(7)O(3))(6)(C(10)H(8)N(2))(2)]·2C(10)H(8)N(2)·2H(2)O, was synthesized under hydrothermal conditions. The centrosymmetric complex consists of two nine-coordinated Nd(3+) cations, six 3-hydroxycinnamate anions and two chelating 2,2′-bipyridine molecules. The coordination geometry around the cations can be best described as distorted tricapped trigonal-prismatic. The carboxylate groups show different coordination and bridging modes. Two of them chelate to one Nd(3+) cation, two bridge the two cations in a bis-monodentate fashion, and two chelate to one and bridge monodentately to the symmetry-related Nd(3+) cation. The dinuclear molecule is surrounded by two 2,2′-bipyridine solvent and two water molecules. Extensive O—H⋯O and O—H⋯N hydrogen-bonding interactions between the components lead to the formation of a three-dimensional network. |
format | Online Article Text |
id | pubmed-3238786 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32387862011-12-23 Tetrakis[μ-3-(3-hydroxyphenyl)propenoato]bis{aqua(2,2′-bipyridine)[3-(3-hydroxyphenyl)propenoato]neodymium(III)} 2,2′-bipyridine disolvate dihydrate Guo, Jing-Ke Wen, Yi-Hang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dinuclear title compound, [Nd(2)(C(9)H(7)O(3))(6)(C(10)H(8)N(2))(2)]·2C(10)H(8)N(2)·2H(2)O, was synthesized under hydrothermal conditions. The centrosymmetric complex consists of two nine-coordinated Nd(3+) cations, six 3-hydroxycinnamate anions and two chelating 2,2′-bipyridine molecules. The coordination geometry around the cations can be best described as distorted tricapped trigonal-prismatic. The carboxylate groups show different coordination and bridging modes. Two of them chelate to one Nd(3+) cation, two bridge the two cations in a bis-monodentate fashion, and two chelate to one and bridge monodentately to the symmetry-related Nd(3+) cation. The dinuclear molecule is surrounded by two 2,2′-bipyridine solvent and two water molecules. Extensive O—H⋯O and O—H⋯N hydrogen-bonding interactions between the components lead to the formation of a three-dimensional network. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238786/ /pubmed/22199663 http://dx.doi.org/10.1107/S1600536811050707 Text en © Guo and Wen 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Guo, Jing-Ke Wen, Yi-Hang Tetrakis[μ-3-(3-hydroxyphenyl)propenoato]bis{aqua(2,2′-bipyridine)[3-(3-hydroxyphenyl)propenoato]neodymium(III)} 2,2′-bipyridine disolvate dihydrate |
title | Tetrakis[μ-3-(3-hydroxyphenyl)propenoato]bis{aqua(2,2′-bipyridine)[3-(3-hydroxyphenyl)propenoato]neodymium(III)} 2,2′-bipyridine disolvate dihydrate |
title_full | Tetrakis[μ-3-(3-hydroxyphenyl)propenoato]bis{aqua(2,2′-bipyridine)[3-(3-hydroxyphenyl)propenoato]neodymium(III)} 2,2′-bipyridine disolvate dihydrate |
title_fullStr | Tetrakis[μ-3-(3-hydroxyphenyl)propenoato]bis{aqua(2,2′-bipyridine)[3-(3-hydroxyphenyl)propenoato]neodymium(III)} 2,2′-bipyridine disolvate dihydrate |
title_full_unstemmed | Tetrakis[μ-3-(3-hydroxyphenyl)propenoato]bis{aqua(2,2′-bipyridine)[3-(3-hydroxyphenyl)propenoato]neodymium(III)} 2,2′-bipyridine disolvate dihydrate |
title_short | Tetrakis[μ-3-(3-hydroxyphenyl)propenoato]bis{aqua(2,2′-bipyridine)[3-(3-hydroxyphenyl)propenoato]neodymium(III)} 2,2′-bipyridine disolvate dihydrate |
title_sort | tetrakis[μ-3-(3-hydroxyphenyl)propenoato]bis{aqua(2,2′-bipyridine)[3-(3-hydroxyphenyl)propenoato]neodymium(iii)} 2,2′-bipyridine disolvate dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238786/ https://www.ncbi.nlm.nih.gov/pubmed/22199663 http://dx.doi.org/10.1107/S1600536811050707 |
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