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Tetrakis[μ-3-(3-hy­droxy­phen­yl)propenoato]bis­{aqua­(2,2′-bipyridine)­[3-(3-hy­droxy­phen­yl)propenoato]neodymium(III)} 2,2′-bipyridine disolvate dihydrate

The dinuclear title compound, [Nd(2)(C(9)H(7)O(3))(6)(C(10)H(8)N(2))(2)]·2C(10)H(8)N(2)·2H(2)O, was synthesized under hydro­thermal conditions. The centrosymmetric complex consists of two nine-coordinated Nd(3+) cations, six 3-hy­droxy­cinnamate anions and two chelating 2,2′-bipyridine mol­ecules. T...

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Detalles Bibliográficos
Autores principales: Guo, Jing-Ke, Wen, Yi-Hang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238786/
https://www.ncbi.nlm.nih.gov/pubmed/22199663
http://dx.doi.org/10.1107/S1600536811050707
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author Guo, Jing-Ke
Wen, Yi-Hang
author_facet Guo, Jing-Ke
Wen, Yi-Hang
author_sort Guo, Jing-Ke
collection PubMed
description The dinuclear title compound, [Nd(2)(C(9)H(7)O(3))(6)(C(10)H(8)N(2))(2)]·2C(10)H(8)N(2)·2H(2)O, was synthesized under hydro­thermal conditions. The centrosymmetric complex consists of two nine-coordinated Nd(3+) cations, six 3-hy­droxy­cinnamate anions and two chelating 2,2′-bipyridine mol­ecules. The coordination geometry around the cations can be best described as distorted tricapped trigonal-prismatic. The carboxyl­ate groups show different coordination and bridging modes. Two of them chelate to one Nd(3+) cation, two bridge the two cations in a bis-monodentate fashion, and two chelate to one and bridge monodentately to the symmetry-related Nd(3+) cation. The dinuclear mol­ecule is surrounded by two 2,2′-bipyridine solvent and two water mol­ecules. Extensive O—H⋯O and O—H⋯N hydrogen-bonding inter­actions between the components lead to the formation of a three-dimensional network.
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spelling pubmed-32387862011-12-23 Tetrakis[μ-3-(3-hy­droxy­phen­yl)propenoato]bis­{aqua­(2,2′-bipyridine)­[3-(3-hy­droxy­phen­yl)propenoato]neodymium(III)} 2,2′-bipyridine disolvate dihydrate Guo, Jing-Ke Wen, Yi-Hang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dinuclear title compound, [Nd(2)(C(9)H(7)O(3))(6)(C(10)H(8)N(2))(2)]·2C(10)H(8)N(2)·2H(2)O, was synthesized under hydro­thermal conditions. The centrosymmetric complex consists of two nine-coordinated Nd(3+) cations, six 3-hy­droxy­cinnamate anions and two chelating 2,2′-bipyridine mol­ecules. The coordination geometry around the cations can be best described as distorted tricapped trigonal-prismatic. The carboxyl­ate groups show different coordination and bridging modes. Two of them chelate to one Nd(3+) cation, two bridge the two cations in a bis-monodentate fashion, and two chelate to one and bridge monodentately to the symmetry-related Nd(3+) cation. The dinuclear mol­ecule is surrounded by two 2,2′-bipyridine solvent and two water mol­ecules. Extensive O—H⋯O and O—H⋯N hydrogen-bonding inter­actions between the components lead to the formation of a three-dimensional network. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238786/ /pubmed/22199663 http://dx.doi.org/10.1107/S1600536811050707 Text en © Guo and Wen 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guo, Jing-Ke
Wen, Yi-Hang
Tetrakis[μ-3-(3-hy­droxy­phen­yl)propenoato]bis­{aqua­(2,2′-bipyridine)­[3-(3-hy­droxy­phen­yl)propenoato]neodymium(III)} 2,2′-bipyridine disolvate dihydrate
title Tetrakis[μ-3-(3-hy­droxy­phen­yl)propenoato]bis­{aqua­(2,2′-bipyridine)­[3-(3-hy­droxy­phen­yl)propenoato]neodymium(III)} 2,2′-bipyridine disolvate dihydrate
title_full Tetrakis[μ-3-(3-hy­droxy­phen­yl)propenoato]bis­{aqua­(2,2′-bipyridine)­[3-(3-hy­droxy­phen­yl)propenoato]neodymium(III)} 2,2′-bipyridine disolvate dihydrate
title_fullStr Tetrakis[μ-3-(3-hy­droxy­phen­yl)propenoato]bis­{aqua­(2,2′-bipyridine)­[3-(3-hy­droxy­phen­yl)propenoato]neodymium(III)} 2,2′-bipyridine disolvate dihydrate
title_full_unstemmed Tetrakis[μ-3-(3-hy­droxy­phen­yl)propenoato]bis­{aqua­(2,2′-bipyridine)­[3-(3-hy­droxy­phen­yl)propenoato]neodymium(III)} 2,2′-bipyridine disolvate dihydrate
title_short Tetrakis[μ-3-(3-hy­droxy­phen­yl)propenoato]bis­{aqua­(2,2′-bipyridine)­[3-(3-hy­droxy­phen­yl)propenoato]neodymium(III)} 2,2′-bipyridine disolvate dihydrate
title_sort tetrakis[μ-3-(3-hy­droxy­phen­yl)propenoato]bis­{aqua­(2,2′-bipyridine)­[3-(3-hy­droxy­phen­yl)propenoato]neodymium(iii)} 2,2′-bipyridine disolvate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238786/
https://www.ncbi.nlm.nih.gov/pubmed/22199663
http://dx.doi.org/10.1107/S1600536811050707
work_keys_str_mv AT guojingke tetrakism33hydroxyphenylpropenoatobisaqua22bipyridine33hydroxyphenylpropenoatoneodymiumiii22bipyridinedisolvatedihydrate
AT wenyihang tetrakism33hydroxyphenylpropenoatobisaqua22bipyridine33hydroxyphenylpropenoatoneodymiumiii22bipyridinedisolvatedihydrate