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Bis(2,2′-bipyridine-κ(2) N,N′)bis[3-(3-hydroxyphenyl)propenoato-κ(2) O (1),O (1′)]cadmium
The title compound, [Cd(C(9)H(7)O(3))(2)(C(10)H(8)N(2))(2)], was synthesized under mild hydrothermal conditions. The structure of the complex molecule consists of four approximately planar fragments: two 3-(3-hydroxyphenyl)propenoate residues and two 2,2′-bipyridine ligands [largest deviation fro...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238787/ https://www.ncbi.nlm.nih.gov/pubmed/22199664 http://dx.doi.org/10.1107/S1600536811050847 |
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author | Zhang, Chun-Yan Wen, Yi-Hang |
author_facet | Zhang, Chun-Yan Wen, Yi-Hang |
author_sort | Zhang, Chun-Yan |
collection | PubMed |
description | The title compound, [Cd(C(9)H(7)O(3))(2)(C(10)H(8)N(2))(2)], was synthesized under mild hydrothermal conditions. The structure of the complex molecule consists of four approximately planar fragments: two 3-(3-hydroxyphenyl)propenoate residues and two 2,2′-bipyridine ligands [largest deviation from the least-squares planes is 0.240 (1) Å for one of 3-(3-hydroxyphenyl)propenoate residues]. The dihedral angles formed by the least-squares planes of the 2,2′-bipyridine ligands and the opposite 3-(3-hydroxyphenyl)propenoate residues are 22.68 (7) and 26.47 (6)°. The CdN(4)O(4) coordination polyhedron can be described as distorted dodecahedral. Intermolecular O—H⋯O hydrogen bonds between carboxylate O atoms and hydroxy groups lead to the formation of chains along the a-axis direction. |
format | Online Article Text |
id | pubmed-3238787 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32387872011-12-23 Bis(2,2′-bipyridine-κ(2) N,N′)bis[3-(3-hydroxyphenyl)propenoato-κ(2) O (1),O (1′)]cadmium Zhang, Chun-Yan Wen, Yi-Hang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cd(C(9)H(7)O(3))(2)(C(10)H(8)N(2))(2)], was synthesized under mild hydrothermal conditions. The structure of the complex molecule consists of four approximately planar fragments: two 3-(3-hydroxyphenyl)propenoate residues and two 2,2′-bipyridine ligands [largest deviation from the least-squares planes is 0.240 (1) Å for one of 3-(3-hydroxyphenyl)propenoate residues]. The dihedral angles formed by the least-squares planes of the 2,2′-bipyridine ligands and the opposite 3-(3-hydroxyphenyl)propenoate residues are 22.68 (7) and 26.47 (6)°. The CdN(4)O(4) coordination polyhedron can be described as distorted dodecahedral. Intermolecular O—H⋯O hydrogen bonds between carboxylate O atoms and hydroxy groups lead to the formation of chains along the a-axis direction. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238787/ /pubmed/22199664 http://dx.doi.org/10.1107/S1600536811050847 Text en © Zhang and Wen 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Chun-Yan Wen, Yi-Hang Bis(2,2′-bipyridine-κ(2) N,N′)bis[3-(3-hydroxyphenyl)propenoato-κ(2) O (1),O (1′)]cadmium |
title | Bis(2,2′-bipyridine-κ(2)
N,N′)bis[3-(3-hydroxyphenyl)propenoato-κ(2)
O
(1),O
(1′)]cadmium |
title_full | Bis(2,2′-bipyridine-κ(2)
N,N′)bis[3-(3-hydroxyphenyl)propenoato-κ(2)
O
(1),O
(1′)]cadmium |
title_fullStr | Bis(2,2′-bipyridine-κ(2)
N,N′)bis[3-(3-hydroxyphenyl)propenoato-κ(2)
O
(1),O
(1′)]cadmium |
title_full_unstemmed | Bis(2,2′-bipyridine-κ(2)
N,N′)bis[3-(3-hydroxyphenyl)propenoato-κ(2)
O
(1),O
(1′)]cadmium |
title_short | Bis(2,2′-bipyridine-κ(2)
N,N′)bis[3-(3-hydroxyphenyl)propenoato-κ(2)
O
(1),O
(1′)]cadmium |
title_sort | bis(2,2′-bipyridine-κ(2)
n,n′)bis[3-(3-hydroxyphenyl)propenoato-κ(2)
o
(1),o
(1′)]cadmium |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238787/ https://www.ncbi.nlm.nih.gov/pubmed/22199664 http://dx.doi.org/10.1107/S1600536811050847 |
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