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Bis(2,2′-bipyridine-κ(2) N,N′)bis­[3-(3-hy­droxyphenyl)propenoato-κ(2) O (1),O (1′)]cadmium

The title compound, [Cd(C(9)H(7)O(3))(2)(C(10)H(8)N(2))(2)], was synthesized under mild hydro­thermal conditions. The structure of the complex mol­ecule consists of four approximately planar fragments: two 3-(3-hy­droxyphenyl)propenoate residues and two 2,2′-bipyridine ligands [largest deviation fro...

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Autores principales: Zhang, Chun-Yan, Wen, Yi-Hang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238787/
https://www.ncbi.nlm.nih.gov/pubmed/22199664
http://dx.doi.org/10.1107/S1600536811050847
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author Zhang, Chun-Yan
Wen, Yi-Hang
author_facet Zhang, Chun-Yan
Wen, Yi-Hang
author_sort Zhang, Chun-Yan
collection PubMed
description The title compound, [Cd(C(9)H(7)O(3))(2)(C(10)H(8)N(2))(2)], was synthesized under mild hydro­thermal conditions. The structure of the complex mol­ecule consists of four approximately planar fragments: two 3-(3-hy­droxyphenyl)propenoate residues and two 2,2′-bipyridine ligands [largest deviation from the least-squares planes is 0.240 (1) Å for one of 3-(3-hy­droxy­phenyl)propenoate residues]. The dihedral angles formed by the least-squares planes of the 2,2′-bipyridine ligands and the opposite 3-(3-hy­droxyphenyl)propenoate residues are 22.68 (7) and 26.47 (6)°. The CdN(4)O(4) coordination polyhedron can be described as distorted dodecahedral. Inter­molecular O—H⋯O hydrogen bonds between carboxyl­ate O atoms and hy­droxy groups lead to the formation of chains along the a-axis direction.
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spelling pubmed-32387872011-12-23 Bis(2,2′-bipyridine-κ(2) N,N′)bis­[3-(3-hy­droxyphenyl)propenoato-κ(2) O (1),O (1′)]cadmium Zhang, Chun-Yan Wen, Yi-Hang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cd(C(9)H(7)O(3))(2)(C(10)H(8)N(2))(2)], was synthesized under mild hydro­thermal conditions. The structure of the complex mol­ecule consists of four approximately planar fragments: two 3-(3-hy­droxyphenyl)propenoate residues and two 2,2′-bipyridine ligands [largest deviation from the least-squares planes is 0.240 (1) Å for one of 3-(3-hy­droxy­phenyl)propenoate residues]. The dihedral angles formed by the least-squares planes of the 2,2′-bipyridine ligands and the opposite 3-(3-hy­droxyphenyl)propenoate residues are 22.68 (7) and 26.47 (6)°. The CdN(4)O(4) coordination polyhedron can be described as distorted dodecahedral. Inter­molecular O—H⋯O hydrogen bonds between carboxyl­ate O atoms and hy­droxy groups lead to the formation of chains along the a-axis direction. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238787/ /pubmed/22199664 http://dx.doi.org/10.1107/S1600536811050847 Text en © Zhang and Wen 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Chun-Yan
Wen, Yi-Hang
Bis(2,2′-bipyridine-κ(2) N,N′)bis­[3-(3-hy­droxyphenyl)propenoato-κ(2) O (1),O (1′)]cadmium
title Bis(2,2′-bipyridine-κ(2) N,N′)bis­[3-(3-hy­droxyphenyl)propenoato-κ(2) O (1),O (1′)]cadmium
title_full Bis(2,2′-bipyridine-κ(2) N,N′)bis­[3-(3-hy­droxyphenyl)propenoato-κ(2) O (1),O (1′)]cadmium
title_fullStr Bis(2,2′-bipyridine-κ(2) N,N′)bis­[3-(3-hy­droxyphenyl)propenoato-κ(2) O (1),O (1′)]cadmium
title_full_unstemmed Bis(2,2′-bipyridine-κ(2) N,N′)bis­[3-(3-hy­droxyphenyl)propenoato-κ(2) O (1),O (1′)]cadmium
title_short Bis(2,2′-bipyridine-κ(2) N,N′)bis­[3-(3-hy­droxyphenyl)propenoato-κ(2) O (1),O (1′)]cadmium
title_sort bis(2,2′-bipyridine-κ(2) n,n′)bis­[3-(3-hy­droxyphenyl)propenoato-κ(2) o (1),o (1′)]cadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238787/
https://www.ncbi.nlm.nih.gov/pubmed/22199664
http://dx.doi.org/10.1107/S1600536811050847
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