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4-Methyl-N′-(2,2,2-trichloroethanimidoyl)benzene-1-carboximidamide
The title compound, C(10)H(10)Cl(3)N(3), features a delocalized unsaturated N C N C N chain and strong intramolecular N—H⋯N hydrogen bonding across the chelate ring and also intramolecular N—H⋯Cl contacts to a CCl(3)-group Cl atom. The only intermolecular contacts in the lattice are non-classical...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238812/ https://www.ncbi.nlm.nih.gov/pubmed/22199665 http://dx.doi.org/10.1107/S1600536811044710 |
Sumario: | The title compound, C(10)H(10)Cl(3)N(3), features a delocalized unsaturated N C N C N chain and strong intramolecular N—H⋯N hydrogen bonding across the chelate ring and also intramolecular N—H⋯Cl contacts to a CCl(3)-group Cl atom. The only intermolecular contacts in the lattice are non-classical hydrogen bonds between methyl and CCl(3) groups. The pseudo-six-membered ring is distinctly non-planar by virtue of rotation about the N—C bond between the carboximidamide and imine components [C—N—C—N torsion angle = −23.6 (2) °]. |
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