4-Methyl-N′-(2,2,2-trichloro­ethanimido­yl)benzene-1-carboximidamide

The title compound, C(10)H(10)Cl(3)N(3), features a delocalized unsaturated N C N C N chain and strong intra­molecular N—H⋯N hydrogen bonding across the chelate ring and also intra­molecular N—H⋯Cl contacts to a CCl(3)-group Cl atom. The only inter­molecular contacts in the lattice are non-classical...

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Detalles Bibliográficos
Autores principales: Roemmele, Tracey L., Boeré, René T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238812/
https://www.ncbi.nlm.nih.gov/pubmed/22199665
http://dx.doi.org/10.1107/S1600536811044710
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author Roemmele, Tracey L.
Boeré, René T.
author_facet Roemmele, Tracey L.
Boeré, René T.
author_sort Roemmele, Tracey L.
collection PubMed
description The title compound, C(10)H(10)Cl(3)N(3), features a delocalized unsaturated N C N C N chain and strong intra­molecular N—H⋯N hydrogen bonding across the chelate ring and also intra­molecular N—H⋯Cl contacts to a CCl(3)-group Cl atom. The only inter­molecular contacts in the lattice are non-classical hydrogen bonds between methyl and CCl(3) groups. The pseudo-six-membered ring is distinctly non-planar by virtue of rotation about the N—C bond between the carboximidamide and imine components [C—N—C—N torsion angle = −23.6 (2) °].
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spelling pubmed-32388122011-12-23 4-Methyl-N′-(2,2,2-trichloro­ethanimido­yl)benzene-1-carboximidamide Roemmele, Tracey L. Boeré, René T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(10)Cl(3)N(3), features a delocalized unsaturated N C N C N chain and strong intra­molecular N—H⋯N hydrogen bonding across the chelate ring and also intra­molecular N—H⋯Cl contacts to a CCl(3)-group Cl atom. The only inter­molecular contacts in the lattice are non-classical hydrogen bonds between methyl and CCl(3) groups. The pseudo-six-membered ring is distinctly non-planar by virtue of rotation about the N—C bond between the carboximidamide and imine components [C—N—C—N torsion angle = −23.6 (2) °]. International Union of Crystallography 2011-11-02 /pmc/articles/PMC3238812/ /pubmed/22199665 http://dx.doi.org/10.1107/S1600536811044710 Text en © Roemmele and Boeré 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Roemmele, Tracey L.
Boeré, René T.
4-Methyl-N′-(2,2,2-trichloro­ethanimido­yl)benzene-1-carboximidamide
title 4-Methyl-N′-(2,2,2-trichloro­ethanimido­yl)benzene-1-carboximidamide
title_full 4-Methyl-N′-(2,2,2-trichloro­ethanimido­yl)benzene-1-carboximidamide
title_fullStr 4-Methyl-N′-(2,2,2-trichloro­ethanimido­yl)benzene-1-carboximidamide
title_full_unstemmed 4-Methyl-N′-(2,2,2-trichloro­ethanimido­yl)benzene-1-carboximidamide
title_short 4-Methyl-N′-(2,2,2-trichloro­ethanimido­yl)benzene-1-carboximidamide
title_sort 4-methyl-n′-(2,2,2-trichloro­ethanimido­yl)benzene-1-carboximidamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238812/
https://www.ncbi.nlm.nih.gov/pubmed/22199665
http://dx.doi.org/10.1107/S1600536811044710
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