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(Z)-2-(5-Chloro-2-oxoindolin-3-ylidene)-N-phenylhydrazinecarbothioamide
In the title compound, C(15)H(11)ClN(4)OS, the dihedral angle between the nine-membered 5-chloroindolin-2-one ring system and the benzene ring is 10.00 (6)°. Intramolecular cyclic N—H⋯O and C—H⋯S hydrogen-bonding interactions [graph set S(6)] are present in the N—N—C—N chain between the ring syst...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238816/ https://www.ncbi.nlm.nih.gov/pubmed/22199669 http://dx.doi.org/10.1107/S1600536811044199 |
Sumario: | In the title compound, C(15)H(11)ClN(4)OS, the dihedral angle between the nine-membered 5-chloroindolin-2-one ring system and the benzene ring is 10.00 (6)°. Intramolecular cyclic N—H⋯O and C—H⋯S hydrogen-bonding interactions [graph set S(6)] are present in the N—N—C—N chain between the ring systems. In the crystal, molecules form centrosymmetric cyclic dimers through intermolecular N—H⋯O hydrogen bonds [graph-set R (2) (2)(8)] and are extended by C—H⋯Cl interactions into infinite chains which propagate along [100]. |
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