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(E)-2,2′-[3-(2-Nitrophenyl)prop-2-ene-1,1-diyl]bis(3-hydroxy-5,5-dimethylcyclohex-2-en-1-one)
In the title compound, C(25)H(29)NO(6), each of the cyclohexenone rings adopts a half-chair conformation. Each of the pairs of hydroxy and carbonyl O atoms are oriented to allow for the formation of intramolecular O—H⋯O hydrogen bonds, which are typical of xanthene derivatives. The nitro group is...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238826/ https://www.ncbi.nlm.nih.gov/pubmed/22199679 http://dx.doi.org/10.1107/S1600536811043686 |
Sumario: | In the title compound, C(25)H(29)NO(6), each of the cyclohexenone rings adopts a half-chair conformation. Each of the pairs of hydroxy and carbonyl O atoms are oriented to allow for the formation of intramolecular O—H⋯O hydrogen bonds, which are typical of xanthene derivatives. The nitro group is rotationally disordered over two orientations in a 0.544 (6):0.456 (6) ratio. In the crystal, weak intermolecualr C—H⋯O hydrogen bonds link molecules into layers parallel to the ab plane. |
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