(E)-2,2′-[3-(2-Nitro­phen­yl)prop-2-ene-1,1-di­yl]bis­(3-hy­droxy-5,5-dimethyl­cyclo­hex-2-en-1-one)

In the title compound, C(25)H(29)NO(6), each of the cyclo­hexenone rings adopts a half-chair conformation. Each of the pairs of hy­droxy and carbonyl O atoms are oriented to allow for the formation of intra­molecular O—H⋯O hydrogen bonds, which are typical of xanthene derivatives. The nitro group is...

Descripción completa

Detalles Bibliográficos
Autores principales: Cha, Joo Hwan, Kim, Young Hee, Min, Sun-Joon, Cho, Yong Seo, Lee, Jae Kyun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238826/
https://www.ncbi.nlm.nih.gov/pubmed/22199679
http://dx.doi.org/10.1107/S1600536811043686
_version_ 1782219063603232768
author Cha, Joo Hwan
Kim, Young Hee
Min, Sun-Joon
Cho, Yong Seo
Lee, Jae Kyun
author_facet Cha, Joo Hwan
Kim, Young Hee
Min, Sun-Joon
Cho, Yong Seo
Lee, Jae Kyun
author_sort Cha, Joo Hwan
collection PubMed
description In the title compound, C(25)H(29)NO(6), each of the cyclo­hexenone rings adopts a half-chair conformation. Each of the pairs of hy­droxy and carbonyl O atoms are oriented to allow for the formation of intra­molecular O—H⋯O hydrogen bonds, which are typical of xanthene derivatives. The nitro group is rotationally disordered over two orientations in a 0.544 (6):0.456 (6) ratio. In the crystal, weak inter­molecualr C—H⋯O hydrogen bonds link mol­ecules into layers parallel to the ab plane.
format Online
Article
Text
id pubmed-3238826
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32388262011-12-23 (E)-2,2′-[3-(2-Nitro­phen­yl)prop-2-ene-1,1-di­yl]bis­(3-hy­droxy-5,5-dimethyl­cyclo­hex-2-en-1-one) Cha, Joo Hwan Kim, Young Hee Min, Sun-Joon Cho, Yong Seo Lee, Jae Kyun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(29)NO(6), each of the cyclo­hexenone rings adopts a half-chair conformation. Each of the pairs of hy­droxy and carbonyl O atoms are oriented to allow for the formation of intra­molecular O—H⋯O hydrogen bonds, which are typical of xanthene derivatives. The nitro group is rotationally disordered over two orientations in a 0.544 (6):0.456 (6) ratio. In the crystal, weak inter­molecualr C—H⋯O hydrogen bonds link mol­ecules into layers parallel to the ab plane. International Union of Crystallography 2011-11-02 /pmc/articles/PMC3238826/ /pubmed/22199679 http://dx.doi.org/10.1107/S1600536811043686 Text en © Cha et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Cha, Joo Hwan
Kim, Young Hee
Min, Sun-Joon
Cho, Yong Seo
Lee, Jae Kyun
(E)-2,2′-[3-(2-Nitro­phen­yl)prop-2-ene-1,1-di­yl]bis­(3-hy­droxy-5,5-dimethyl­cyclo­hex-2-en-1-one)
title (E)-2,2′-[3-(2-Nitro­phen­yl)prop-2-ene-1,1-di­yl]bis­(3-hy­droxy-5,5-dimethyl­cyclo­hex-2-en-1-one)
title_full (E)-2,2′-[3-(2-Nitro­phen­yl)prop-2-ene-1,1-di­yl]bis­(3-hy­droxy-5,5-dimethyl­cyclo­hex-2-en-1-one)
title_fullStr (E)-2,2′-[3-(2-Nitro­phen­yl)prop-2-ene-1,1-di­yl]bis­(3-hy­droxy-5,5-dimethyl­cyclo­hex-2-en-1-one)
title_full_unstemmed (E)-2,2′-[3-(2-Nitro­phen­yl)prop-2-ene-1,1-di­yl]bis­(3-hy­droxy-5,5-dimethyl­cyclo­hex-2-en-1-one)
title_short (E)-2,2′-[3-(2-Nitro­phen­yl)prop-2-ene-1,1-di­yl]bis­(3-hy­droxy-5,5-dimethyl­cyclo­hex-2-en-1-one)
title_sort (e)-2,2′-[3-(2-nitro­phen­yl)prop-2-ene-1,1-di­yl]bis­(3-hy­droxy-5,5-dimethyl­cyclo­hex-2-en-1-one)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238826/
https://www.ncbi.nlm.nih.gov/pubmed/22199679
http://dx.doi.org/10.1107/S1600536811043686
work_keys_str_mv AT chajoohwan e2232nitrophenylprop2ene11diylbis3hydroxy55dimethylcyclohex2en1one
AT kimyounghee e2232nitrophenylprop2ene11diylbis3hydroxy55dimethylcyclohex2en1one
AT minsunjoon e2232nitrophenylprop2ene11diylbis3hydroxy55dimethylcyclohex2en1one
AT choyongseo e2232nitrophenylprop2ene11diylbis3hydroxy55dimethylcyclohex2en1one
AT leejaekyun e2232nitrophenylprop2ene11diylbis3hydroxy55dimethylcyclohex2en1one

Ejemplares similares