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1,1,1,5,5,5-Hexafluoro-2,4-dimethoxypentane-2,4-diol
The title compound, C(7)H(10)F(6)O(4), was isolated as an unexpected product from a reaction of tantalum(V) methoxide with hexafluoroacetylacetone in a methanol solution. The asymmetric unit consists of one half-molecule with the middle C atom lying on a twofold axis. The crystal structure is st...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238828/ https://www.ncbi.nlm.nih.gov/pubmed/22199681 http://dx.doi.org/10.1107/S1600536811044813 |
Sumario: | The title compound, C(7)H(10)F(6)O(4), was isolated as an unexpected product from a reaction of tantalum(V) methoxide with hexafluoroacetylacetone in a methanol solution. The asymmetric unit consists of one half-molecule with the middle C atom lying on a twofold axis. The crystal structure is stabilized by O—H⋯O and an array of C—H⋯F hydrogen-bonding interactions. These interactions link the molecules into a stable supramolecular three-dimensional network. The molecules pack in a ribbon-like form in the ac plane as a result of these interactions. |
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