1,1,1,5,5,5-Hexafluoro-2,4-dimeth­oxy­pentane-2,4-diol

The title compound, C(7)H(10)F(6)O(4), was isolated as an unexpected product from a reaction of tantalum(V) methoxide with hexa­fluoro­acetyl­acetone in a methanol solution. The asymmetric unit consists of one half-mol­ecule with the middle C atom lying on a twofold axis. The crystal structure is st...

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Detalles Bibliográficos
Autores principales: Koen, Renier, Roodt, Andreas, Visser, Hendrik G., Muller, Theunis J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238828/
https://www.ncbi.nlm.nih.gov/pubmed/22199681
http://dx.doi.org/10.1107/S1600536811044813
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author Koen, Renier
Roodt, Andreas
Visser, Hendrik G.
Muller, Theunis J.
author_facet Koen, Renier
Roodt, Andreas
Visser, Hendrik G.
Muller, Theunis J.
author_sort Koen, Renier
collection PubMed
description The title compound, C(7)H(10)F(6)O(4), was isolated as an unexpected product from a reaction of tantalum(V) methoxide with hexa­fluoro­acetyl­acetone in a methanol solution. The asymmetric unit consists of one half-mol­ecule with the middle C atom lying on a twofold axis. The crystal structure is stabilized by O—H⋯O and an array of C—H⋯F hydrogen-bonding inter­actions. These inter­actions link the mol­ecules into a stable supra­molecular three-dimensional network. The mol­ecules pack in a ribbon-like form in the ac plane as a result of these inter­actions.
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spelling pubmed-32388282011-12-23 1,1,1,5,5,5-Hexafluoro-2,4-dimeth­oxy­pentane-2,4-diol Koen, Renier Roodt, Andreas Visser, Hendrik G. Muller, Theunis J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(7)H(10)F(6)O(4), was isolated as an unexpected product from a reaction of tantalum(V) methoxide with hexa­fluoro­acetyl­acetone in a methanol solution. The asymmetric unit consists of one half-mol­ecule with the middle C atom lying on a twofold axis. The crystal structure is stabilized by O—H⋯O and an array of C—H⋯F hydrogen-bonding inter­actions. These inter­actions link the mol­ecules into a stable supra­molecular three-dimensional network. The mol­ecules pack in a ribbon-like form in the ac plane as a result of these inter­actions. International Union of Crystallography 2011-11-02 /pmc/articles/PMC3238828/ /pubmed/22199681 http://dx.doi.org/10.1107/S1600536811044813 Text en © Koen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Koen, Renier
Roodt, Andreas
Visser, Hendrik G.
Muller, Theunis J.
1,1,1,5,5,5-Hexafluoro-2,4-dimeth­oxy­pentane-2,4-diol
title 1,1,1,5,5,5-Hexafluoro-2,4-dimeth­oxy­pentane-2,4-diol
title_full 1,1,1,5,5,5-Hexafluoro-2,4-dimeth­oxy­pentane-2,4-diol
title_fullStr 1,1,1,5,5,5-Hexafluoro-2,4-dimeth­oxy­pentane-2,4-diol
title_full_unstemmed 1,1,1,5,5,5-Hexafluoro-2,4-dimeth­oxy­pentane-2,4-diol
title_short 1,1,1,5,5,5-Hexafluoro-2,4-dimeth­oxy­pentane-2,4-diol
title_sort 1,1,1,5,5,5-hexafluoro-2,4-dimeth­oxy­pentane-2,4-diol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238828/
https://www.ncbi.nlm.nih.gov/pubmed/22199681
http://dx.doi.org/10.1107/S1600536811044813
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