4-(4-Bromo­phen­yl)-3-methyl-1-phenyl-6,7-dihydro-1H-pyrazolo­[3,4-b]thieno[2,3-e]pyridine 5,5-dioxide

In the title compound, C(21)H(16)BrN(3)O(2)S, the pyrazole and pyridine rings are nearly coplanar, the dihedral angle between their planes being 3.17 (14)°. The 2,3-dihydro­thio­phene ring adopts an envelope conformation. The 4-bromo­phen­yl/pyridine ring and phen­yl/pyrazole rings form dihedral ang...

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Detalles Bibliográficos
Autores principales: Li, Tuanjie, Zhang, Honghong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238837/
https://www.ncbi.nlm.nih.gov/pubmed/22199690
http://dx.doi.org/10.1107/S1600536811045697
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author Li, Tuanjie
Zhang, Honghong
author_facet Li, Tuanjie
Zhang, Honghong
author_sort Li, Tuanjie
collection PubMed
description In the title compound, C(21)H(16)BrN(3)O(2)S, the pyrazole and pyridine rings are nearly coplanar, the dihedral angle between their planes being 3.17 (14)°. The 2,3-dihydro­thio­phene ring adopts an envelope conformation. The 4-bromo­phen­yl/pyridine ring and phen­yl/pyrazole rings form dihedral angles of 60.06 (9) and 33.49 (11)°, respectively. There is an intra­molecular C—H⋯N hydrogen bond. The crystal packing is stabilized by inter­molecular C—H⋯O hydrogen bonding and C—H⋯π inter­actions.
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spelling pubmed-32388372011-12-23 4-(4-Bromo­phen­yl)-3-methyl-1-phenyl-6,7-dihydro-1H-pyrazolo­[3,4-b]thieno[2,3-e]pyridine 5,5-dioxide Li, Tuanjie Zhang, Honghong Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(16)BrN(3)O(2)S, the pyrazole and pyridine rings are nearly coplanar, the dihedral angle between their planes being 3.17 (14)°. The 2,3-dihydro­thio­phene ring adopts an envelope conformation. The 4-bromo­phen­yl/pyridine ring and phen­yl/pyrazole rings form dihedral angles of 60.06 (9) and 33.49 (11)°, respectively. There is an intra­molecular C—H⋯N hydrogen bond. The crystal packing is stabilized by inter­molecular C—H⋯O hydrogen bonding and C—H⋯π inter­actions. International Union of Crystallography 2011-11-05 /pmc/articles/PMC3238837/ /pubmed/22199690 http://dx.doi.org/10.1107/S1600536811045697 Text en © Li and Zhang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Tuanjie
Zhang, Honghong
4-(4-Bromo­phen­yl)-3-methyl-1-phenyl-6,7-dihydro-1H-pyrazolo­[3,4-b]thieno[2,3-e]pyridine 5,5-dioxide
title 4-(4-Bromo­phen­yl)-3-methyl-1-phenyl-6,7-dihydro-1H-pyrazolo­[3,4-b]thieno[2,3-e]pyridine 5,5-dioxide
title_full 4-(4-Bromo­phen­yl)-3-methyl-1-phenyl-6,7-dihydro-1H-pyrazolo­[3,4-b]thieno[2,3-e]pyridine 5,5-dioxide
title_fullStr 4-(4-Bromo­phen­yl)-3-methyl-1-phenyl-6,7-dihydro-1H-pyrazolo­[3,4-b]thieno[2,3-e]pyridine 5,5-dioxide
title_full_unstemmed 4-(4-Bromo­phen­yl)-3-methyl-1-phenyl-6,7-dihydro-1H-pyrazolo­[3,4-b]thieno[2,3-e]pyridine 5,5-dioxide
title_short 4-(4-Bromo­phen­yl)-3-methyl-1-phenyl-6,7-dihydro-1H-pyrazolo­[3,4-b]thieno[2,3-e]pyridine 5,5-dioxide
title_sort 4-(4-bromo­phen­yl)-3-methyl-1-phenyl-6,7-dihydro-1h-pyrazolo­[3,4-b]thieno[2,3-e]pyridine 5,5-dioxide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238837/
https://www.ncbi.nlm.nih.gov/pubmed/22199690
http://dx.doi.org/10.1107/S1600536811045697
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AT zhanghonghong 44bromophenyl3methyl1phenyl67dihydro1hpyrazolo34bthieno23epyridine55dioxide

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