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1-[2-(1H-Benzimidazol-2-yl)eth­yl]-1H-1,2,3-benzotriazole

In the title compound, C(15)H(13)N(5), the N-containing heterocycles are linked by an ethyl­ene spacer in a gauche conformation, the N—C—C—C torsion angle along the linker being 60.1 (3)°. The dihedral angle between the terminal benzotriazole and benzimidazole rings is 39.02 (6)°. In the crystal, ad...

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Detalles Bibliográficos
Autores principales: Zhang, Zhong, Lu, Wei, Wu, Difeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238838/
https://www.ncbi.nlm.nih.gov/pubmed/22199691
http://dx.doi.org/10.1107/S1600536811045442
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author Zhang, Zhong
Lu, Wei
Wu, Difeng
author_facet Zhang, Zhong
Lu, Wei
Wu, Difeng
author_sort Zhang, Zhong
collection PubMed
description In the title compound, C(15)H(13)N(5), the N-containing heterocycles are linked by an ethyl­ene spacer in a gauche conformation, the N—C—C—C torsion angle along the linker being 60.1 (3)°. The dihedral angle between the terminal benzotriazole and benzimidazole rings is 39.02 (6)°. In the crystal, adjacent mol­ecules are connected by N—H⋯N hydrogen bonds, forming an infinite chain along the c axis. π–π stacking inter­actions [centroid–centroid distance = 3.8772 (7) Å] between the benzotriazole rings of neighbouring chains extend these chains into a supra­molecular sheet in the bc plane. Weak inter­molecular C—H⋯N inter­actions further stabilize the crystal structure.
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spelling pubmed-32388382011-12-23 1-[2-(1H-Benzimidazol-2-yl)eth­yl]-1H-1,2,3-benzotriazole Zhang, Zhong Lu, Wei Wu, Difeng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(13)N(5), the N-containing heterocycles are linked by an ethyl­ene spacer in a gauche conformation, the N—C—C—C torsion angle along the linker being 60.1 (3)°. The dihedral angle between the terminal benzotriazole and benzimidazole rings is 39.02 (6)°. In the crystal, adjacent mol­ecules are connected by N—H⋯N hydrogen bonds, forming an infinite chain along the c axis. π–π stacking inter­actions [centroid–centroid distance = 3.8772 (7) Å] between the benzotriazole rings of neighbouring chains extend these chains into a supra­molecular sheet in the bc plane. Weak inter­molecular C—H⋯N inter­actions further stabilize the crystal structure. International Union of Crystallography 2011-11-05 /pmc/articles/PMC3238838/ /pubmed/22199691 http://dx.doi.org/10.1107/S1600536811045442 Text en © Zhang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Zhong
Lu, Wei
Wu, Difeng
1-[2-(1H-Benzimidazol-2-yl)eth­yl]-1H-1,2,3-benzotriazole
title 1-[2-(1H-Benzimidazol-2-yl)eth­yl]-1H-1,2,3-benzotriazole
title_full 1-[2-(1H-Benzimidazol-2-yl)eth­yl]-1H-1,2,3-benzotriazole
title_fullStr 1-[2-(1H-Benzimidazol-2-yl)eth­yl]-1H-1,2,3-benzotriazole
title_full_unstemmed 1-[2-(1H-Benzimidazol-2-yl)eth­yl]-1H-1,2,3-benzotriazole
title_short 1-[2-(1H-Benzimidazol-2-yl)eth­yl]-1H-1,2,3-benzotriazole
title_sort 1-[2-(1h-benzimidazol-2-yl)eth­yl]-1h-1,2,3-benzotriazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238838/
https://www.ncbi.nlm.nih.gov/pubmed/22199691
http://dx.doi.org/10.1107/S1600536811045442
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