(E)-1-(4,4′′-Difluoro-5′-meth­oxy-1,1′:3′,1′′-terphenyl-4′-yl)-3-(4-methyl­phen­yl)prop-2-en-1-one

In the meta-terphenyl fragment of the title mol­ecule, C(29)H(22)F(2)O(2), the two fluoro­phenyl rings are twisted from the central benzene ring by 46.72 (6) and 41.70 (6)°, respectively. In the crystal, weak C—H⋯O and C—H⋯F hydrogen bonds link the mol­ecules into layers parallel to the ab plane. Th...

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Detalles Bibliográficos
Autores principales: Betz, Richard, Gerber, Thomas, Hosten, Eric, Samshuddin, Seranthimata, Narayana, Badiadka, Yathirajan, Hemmige S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238850/
https://www.ncbi.nlm.nih.gov/pubmed/22199703
http://dx.doi.org/10.1107/S160053681104579X
Descripción
Sumario:In the meta-terphenyl fragment of the title mol­ecule, C(29)H(22)F(2)O(2), the two fluoro­phenyl rings are twisted from the central benzene ring by 46.72 (6) and 41.70 (6)°, respectively. In the crystal, weak C—H⋯O and C—H⋯F hydrogen bonds link the mol­ecules into layers parallel to the ab plane. The crystal packing exhibits π–π inter­actions, the shortest distance between the centroids of aromatic rings being 3.6364 (7) Å.

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