(E)-1-(2,4-Dinitro­phen­yl)-2-[1-(2-meth­oxy­phen­yl)ethyl­idene]hydrazine

The mol­ecule of the title compound, C(15)H(14)N(4)O(5), is in an E conformation with respect to the C=N double bond and the dihedral angle between the two benzene rings is 37.83 (7)°. The ethyl­idenehydrazine plane makes dihedral angles of 4.93 (9) and 42.38 (9)° with the two benzene rings. An intr...

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Autores principales: Fun, Hoong-Kun, Nilwanna, Boonlerd, Jansrisewangwong, Patcharaporn, Kobkeatthawin, Thawanrat, Chantrapromma, Suchada
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238869/
https://www.ncbi.nlm.nih.gov/pubmed/22199722
http://dx.doi.org/10.1107/S1600536811045417
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author Fun, Hoong-Kun
Nilwanna, Boonlerd
Jansrisewangwong, Patcharaporn
Kobkeatthawin, Thawanrat
Chantrapromma, Suchada
author_facet Fun, Hoong-Kun
Nilwanna, Boonlerd
Jansrisewangwong, Patcharaporn
Kobkeatthawin, Thawanrat
Chantrapromma, Suchada
author_sort Fun, Hoong-Kun
collection PubMed
description The mol­ecule of the title compound, C(15)H(14)N(4)O(5), is in an E conformation with respect to the C=N double bond and the dihedral angle between the two benzene rings is 37.83 (7)°. The ethyl­idenehydrazine plane makes dihedral angles of 4.93 (9) and 42.38 (9)° with the two benzene rings. An intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, mol­ecules are linked by weak C—H⋯O inter­actions into chains along the c axis which are stacked along the b axis by aromatic π–π inter­actions with a centroid–centroid distance of 3.5927 (10) Å.
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spelling pubmed-32388692011-12-23 (E)-1-(2,4-Dinitro­phen­yl)-2-[1-(2-meth­oxy­phen­yl)ethyl­idene]hydrazine Fun, Hoong-Kun Nilwanna, Boonlerd Jansrisewangwong, Patcharaporn Kobkeatthawin, Thawanrat Chantrapromma, Suchada Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(15)H(14)N(4)O(5), is in an E conformation with respect to the C=N double bond and the dihedral angle between the two benzene rings is 37.83 (7)°. The ethyl­idenehydrazine plane makes dihedral angles of 4.93 (9) and 42.38 (9)° with the two benzene rings. An intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, mol­ecules are linked by weak C—H⋯O inter­actions into chains along the c axis which are stacked along the b axis by aromatic π–π inter­actions with a centroid–centroid distance of 3.5927 (10) Å. International Union of Crystallography 2011-11-05 /pmc/articles/PMC3238869/ /pubmed/22199722 http://dx.doi.org/10.1107/S1600536811045417 Text en © Fun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Nilwanna, Boonlerd
Jansrisewangwong, Patcharaporn
Kobkeatthawin, Thawanrat
Chantrapromma, Suchada
(E)-1-(2,4-Dinitro­phen­yl)-2-[1-(2-meth­oxy­phen­yl)ethyl­idene]hydrazine
title (E)-1-(2,4-Dinitro­phen­yl)-2-[1-(2-meth­oxy­phen­yl)ethyl­idene]hydrazine
title_full (E)-1-(2,4-Dinitro­phen­yl)-2-[1-(2-meth­oxy­phen­yl)ethyl­idene]hydrazine
title_fullStr (E)-1-(2,4-Dinitro­phen­yl)-2-[1-(2-meth­oxy­phen­yl)ethyl­idene]hydrazine
title_full_unstemmed (E)-1-(2,4-Dinitro­phen­yl)-2-[1-(2-meth­oxy­phen­yl)ethyl­idene]hydrazine
title_short (E)-1-(2,4-Dinitro­phen­yl)-2-[1-(2-meth­oxy­phen­yl)ethyl­idene]hydrazine
title_sort (e)-1-(2,4-dinitro­phen­yl)-2-[1-(2-meth­oxy­phen­yl)ethyl­idene]hydrazine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238869/
https://www.ncbi.nlm.nih.gov/pubmed/22199722
http://dx.doi.org/10.1107/S1600536811045417
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