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9-(2,5-Dimethyl­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate

In the title compound, C(23)H(20)NO(2) (+)·CF(3)SO(3) (−), the acridine ring system is oriented at a dihedral angle of 23.1 (1)° with respect to the benzene ring and the carboxyl group is twisted at an angle of 74.1 (1)° relative to the acridine skeleton. In the crystal, adjacent cations are linked...

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Detalles Bibliográficos
Autores principales: Trzybiński, Damian, Krzymiński, Karol, Błażejowski, Jerzy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238871/
https://www.ncbi.nlm.nih.gov/pubmed/22199724
http://dx.doi.org/10.1107/S1600536811045090
Descripción
Sumario:In the title compound, C(23)H(20)NO(2) (+)·CF(3)SO(3) (−), the acridine ring system is oriented at a dihedral angle of 23.1 (1)° with respect to the benzene ring and the carboxyl group is twisted at an angle of 74.1 (1)° relative to the acridine skeleton. In the crystal, adjacent cations are linked through C—H⋯π inter­actions and neighboring cations and anions via weak C—H⋯O hydrogen bonds. The mean planes of adjacent acridine units are either parallel or inclined at angles of 15.0 (1), 26.9 (1) and 48.1 (1)° in the crystal structure.