9-(2,5-Dimethyl­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate

In the title compound, C(23)H(20)NO(2) (+)·CF(3)SO(3) (−), the acridine ring system is oriented at a dihedral angle of 23.1 (1)° with respect to the benzene ring and the carboxyl group is twisted at an angle of 74.1 (1)° relative to the acridine skeleton. In the crystal, adjacent cations are linked...

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Detalles Bibliográficos
Autores principales: Trzybiński, Damian, Krzymiński, Karol, Błażejowski, Jerzy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238871/
https://www.ncbi.nlm.nih.gov/pubmed/22199724
http://dx.doi.org/10.1107/S1600536811045090
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author Trzybiński, Damian
Krzymiński, Karol
Błażejowski, Jerzy
author_facet Trzybiński, Damian
Krzymiński, Karol
Błażejowski, Jerzy
author_sort Trzybiński, Damian
collection PubMed
description In the title compound, C(23)H(20)NO(2) (+)·CF(3)SO(3) (−), the acridine ring system is oriented at a dihedral angle of 23.1 (1)° with respect to the benzene ring and the carboxyl group is twisted at an angle of 74.1 (1)° relative to the acridine skeleton. In the crystal, adjacent cations are linked through C—H⋯π inter­actions and neighboring cations and anions via weak C—H⋯O hydrogen bonds. The mean planes of adjacent acridine units are either parallel or inclined at angles of 15.0 (1), 26.9 (1) and 48.1 (1)° in the crystal structure.
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spelling pubmed-32388712011-12-23 9-(2,5-Dimethyl­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate Trzybiński, Damian Krzymiński, Karol Błażejowski, Jerzy Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(23)H(20)NO(2) (+)·CF(3)SO(3) (−), the acridine ring system is oriented at a dihedral angle of 23.1 (1)° with respect to the benzene ring and the carboxyl group is twisted at an angle of 74.1 (1)° relative to the acridine skeleton. In the crystal, adjacent cations are linked through C—H⋯π inter­actions and neighboring cations and anions via weak C—H⋯O hydrogen bonds. The mean planes of adjacent acridine units are either parallel or inclined at angles of 15.0 (1), 26.9 (1) and 48.1 (1)° in the crystal structure. International Union of Crystallography 2011-11-05 /pmc/articles/PMC3238871/ /pubmed/22199724 http://dx.doi.org/10.1107/S1600536811045090 Text en © Trzybiński et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Trzybiński, Damian
Krzymiński, Karol
Błażejowski, Jerzy
9-(2,5-Dimethyl­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title 9-(2,5-Dimethyl­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_full 9-(2,5-Dimethyl­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_fullStr 9-(2,5-Dimethyl­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_full_unstemmed 9-(2,5-Dimethyl­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_short 9-(2,5-Dimethyl­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_sort 9-(2,5-dimethyl­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238871/
https://www.ncbi.nlm.nih.gov/pubmed/22199724
http://dx.doi.org/10.1107/S1600536811045090
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AT błazejowskijerzy 925dimethylphenoxycarbonyl10methylacridiniumtrifluoromethanesulfonate

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