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5′′-(4-Methoxybenzylidene)-7′-(4-methoxyphenyl)-1′′-methyl-5′,6′,7′,7a’-tetrahydrodispiro[acenaphthene-1,5′-pyrrolo[1,2-c][1,3]thiazole-6′,3′′-piperidine]-2,4′′-dione
In the title compound, C(37)H(34)N(2)O(4)S, the piperidine ring adopts a half-chair conformation. The thiazole ring adopts a slightly twisted envelope conformation and the pyrrole ring adopts an envelope conformation; in each case, the C atom linking the rings is the flap atom. An intramolecular C...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238875/ https://www.ncbi.nlm.nih.gov/pubmed/22199728 http://dx.doi.org/10.1107/S1600536811045934 |
| _version_ | 1782219074616426496 |
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| author | Suresh, J. Vishnupriya, R. Kumar, R. Ranjith Sivakumar, S. Lakshman, P. L. Nilantha |
| author_facet | Suresh, J. Vishnupriya, R. Kumar, R. Ranjith Sivakumar, S. Lakshman, P. L. Nilantha |
| author_sort | Suresh, J. |
| collection | PubMed |
| description | In the title compound, C(37)H(34)N(2)O(4)S, the piperidine ring adopts a half-chair conformation. The thiazole ring adopts a slightly twisted envelope conformation and the pyrrole ring adopts an envelope conformation; in each case, the C atom linking the rings is the flap atom. An intramolecular C—H⋯O interaction is noted. The crystal structure is stabilized by C—H⋯O and C—H⋯π interactions. |
| format | Online Article Text |
| id | pubmed-3238875 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32388752011-12-23 5′′-(4-Methoxybenzylidene)-7′-(4-methoxyphenyl)-1′′-methyl-5′,6′,7′,7a’-tetrahydrodispiro[acenaphthene-1,5′-pyrrolo[1,2-c][1,3]thiazole-6′,3′′-piperidine]-2,4′′-dione Suresh, J. Vishnupriya, R. Kumar, R. Ranjith Sivakumar, S. Lakshman, P. L. Nilantha Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(37)H(34)N(2)O(4)S, the piperidine ring adopts a half-chair conformation. The thiazole ring adopts a slightly twisted envelope conformation and the pyrrole ring adopts an envelope conformation; in each case, the C atom linking the rings is the flap atom. An intramolecular C—H⋯O interaction is noted. The crystal structure is stabilized by C—H⋯O and C—H⋯π interactions. International Union of Crystallography 2011-11-05 /pmc/articles/PMC3238875/ /pubmed/22199728 http://dx.doi.org/10.1107/S1600536811045934 Text en © Suresh et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Suresh, J. Vishnupriya, R. Kumar, R. Ranjith Sivakumar, S. Lakshman, P. L. Nilantha 5′′-(4-Methoxybenzylidene)-7′-(4-methoxyphenyl)-1′′-methyl-5′,6′,7′,7a’-tetrahydrodispiro[acenaphthene-1,5′-pyrrolo[1,2-c][1,3]thiazole-6′,3′′-piperidine]-2,4′′-dione |
| title | 5′′-(4-Methoxybenzylidene)-7′-(4-methoxyphenyl)-1′′-methyl-5′,6′,7′,7a’-tetrahydrodispiro[acenaphthene-1,5′-pyrrolo[1,2-c][1,3]thiazole-6′,3′′-piperidine]-2,4′′-dione |
| title_full | 5′′-(4-Methoxybenzylidene)-7′-(4-methoxyphenyl)-1′′-methyl-5′,6′,7′,7a’-tetrahydrodispiro[acenaphthene-1,5′-pyrrolo[1,2-c][1,3]thiazole-6′,3′′-piperidine]-2,4′′-dione |
| title_fullStr | 5′′-(4-Methoxybenzylidene)-7′-(4-methoxyphenyl)-1′′-methyl-5′,6′,7′,7a’-tetrahydrodispiro[acenaphthene-1,5′-pyrrolo[1,2-c][1,3]thiazole-6′,3′′-piperidine]-2,4′′-dione |
| title_full_unstemmed | 5′′-(4-Methoxybenzylidene)-7′-(4-methoxyphenyl)-1′′-methyl-5′,6′,7′,7a’-tetrahydrodispiro[acenaphthene-1,5′-pyrrolo[1,2-c][1,3]thiazole-6′,3′′-piperidine]-2,4′′-dione |
| title_short | 5′′-(4-Methoxybenzylidene)-7′-(4-methoxyphenyl)-1′′-methyl-5′,6′,7′,7a’-tetrahydrodispiro[acenaphthene-1,5′-pyrrolo[1,2-c][1,3]thiazole-6′,3′′-piperidine]-2,4′′-dione |
| title_sort | 5′′-(4-methoxybenzylidene)-7′-(4-methoxyphenyl)-1′′-methyl-5′,6′,7′,7a’-tetrahydrodispiro[acenaphthene-1,5′-pyrrolo[1,2-c][1,3]thiazole-6′,3′′-piperidine]-2,4′′-dione |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238875/ https://www.ncbi.nlm.nih.gov/pubmed/22199728 http://dx.doi.org/10.1107/S1600536811045934 |
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