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7′-Phenyl-5′,6′,7′,7a′-tetrahydrodipiro[indan-2,5′-pyrrolo[1,2-c][1,3]thiazole-6′,2′′-indan]-1,3,1′′-trione
The asymmetric unit of the title compound, C(28)H(21)NO(3)S, contains two molecules with similar geometries. The thiazolidine rings adopt half-chair conformations while the pyrrolidine and the diketo-substituted five-membered carbocyclic rings are in envelope conformations with the spiro C atoms a...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238881/ https://www.ncbi.nlm.nih.gov/pubmed/22199734 http://dx.doi.org/10.1107/S1600536811046174 |
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author | Wei, Ang Chee Ali, Mohamed Ashraf Choon, Tan Soo Quah, Ching Kheng Fun, Hoong-Kun |
author_facet | Wei, Ang Chee Ali, Mohamed Ashraf Choon, Tan Soo Quah, Ching Kheng Fun, Hoong-Kun |
author_sort | Wei, Ang Chee |
collection | PubMed |
description | The asymmetric unit of the title compound, C(28)H(21)NO(3)S, contains two molecules with similar geometries. The thiazolidine rings adopt half-chair conformations while the pyrrolidine and the diketo-substituted five-membered carbocyclic rings are in envelope conformations with the spiro C atoms at the flaps. In one molecule, the phenyl ring forms dihedral angles of 57.76 (12) and 71.79 (12)° with the fused benzene rings and the fused benzene rings form a dihedral angle of 57.75 (13)°. The corresponding dihedral angles in the other molecule are 60.04 (12), 72.93 (12) and 54.51 (13)°. The molecular structure is stabilized by intramolecular C—H⋯O hydrogen bonds, which generate S(6) ring motifs. In the crystal, molecules are linked via C—H⋯O and C—H⋯N hydrogen bonds into layers lying parallel to the ab plane. |
format | Online Article Text |
id | pubmed-3238881 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32388812011-12-23 7′-Phenyl-5′,6′,7′,7a′-tetrahydrodipiro[indan-2,5′-pyrrolo[1,2-c][1,3]thiazole-6′,2′′-indan]-1,3,1′′-trione Wei, Ang Chee Ali, Mohamed Ashraf Choon, Tan Soo Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(28)H(21)NO(3)S, contains two molecules with similar geometries. The thiazolidine rings adopt half-chair conformations while the pyrrolidine and the diketo-substituted five-membered carbocyclic rings are in envelope conformations with the spiro C atoms at the flaps. In one molecule, the phenyl ring forms dihedral angles of 57.76 (12) and 71.79 (12)° with the fused benzene rings and the fused benzene rings form a dihedral angle of 57.75 (13)°. The corresponding dihedral angles in the other molecule are 60.04 (12), 72.93 (12) and 54.51 (13)°. The molecular structure is stabilized by intramolecular C—H⋯O hydrogen bonds, which generate S(6) ring motifs. In the crystal, molecules are linked via C—H⋯O and C—H⋯N hydrogen bonds into layers lying parallel to the ab plane. International Union of Crystallography 2011-11-05 /pmc/articles/PMC3238881/ /pubmed/22199734 http://dx.doi.org/10.1107/S1600536811046174 Text en © Wei et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Wei, Ang Chee Ali, Mohamed Ashraf Choon, Tan Soo Quah, Ching Kheng Fun, Hoong-Kun 7′-Phenyl-5′,6′,7′,7a′-tetrahydrodipiro[indan-2,5′-pyrrolo[1,2-c][1,3]thiazole-6′,2′′-indan]-1,3,1′′-trione |
title | 7′-Phenyl-5′,6′,7′,7a′-tetrahydrodipiro[indan-2,5′-pyrrolo[1,2-c][1,3]thiazole-6′,2′′-indan]-1,3,1′′-trione |
title_full | 7′-Phenyl-5′,6′,7′,7a′-tetrahydrodipiro[indan-2,5′-pyrrolo[1,2-c][1,3]thiazole-6′,2′′-indan]-1,3,1′′-trione |
title_fullStr | 7′-Phenyl-5′,6′,7′,7a′-tetrahydrodipiro[indan-2,5′-pyrrolo[1,2-c][1,3]thiazole-6′,2′′-indan]-1,3,1′′-trione |
title_full_unstemmed | 7′-Phenyl-5′,6′,7′,7a′-tetrahydrodipiro[indan-2,5′-pyrrolo[1,2-c][1,3]thiazole-6′,2′′-indan]-1,3,1′′-trione |
title_short | 7′-Phenyl-5′,6′,7′,7a′-tetrahydrodipiro[indan-2,5′-pyrrolo[1,2-c][1,3]thiazole-6′,2′′-indan]-1,3,1′′-trione |
title_sort | 7′-phenyl-5′,6′,7′,7a′-tetrahydrodipiro[indan-2,5′-pyrrolo[1,2-c][1,3]thiazole-6′,2′′-indan]-1,3,1′′-trione |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238881/ https://www.ncbi.nlm.nih.gov/pubmed/22199734 http://dx.doi.org/10.1107/S1600536811046174 |
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