N,N-Dimethyl-N′,N′′-diphenyl­phospho­ric triamide

In the title compound, C(14)H(18)N(3)OP, a crystallographic mirror plane bis­ects the mol­ecule (the C,N,C atoms of the dimethyl­amido moiety and the P=O unit lie on the mirror plane). The P atom has a distorted tetra­hedral geometry; the bond angles at P are in the range 98.98 (11)–115.28 (7)°. In...

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Autores principales: Pourayoubi, Mehrdad, Yousefi, Mohammad, Eslami, Farnaz, Rheingold, Arnold L., Chen, Chao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238882/
https://www.ncbi.nlm.nih.gov/pubmed/22199735
http://dx.doi.org/10.1107/S1600536811046058
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author Pourayoubi, Mehrdad
Yousefi, Mohammad
Eslami, Farnaz
Rheingold, Arnold L.
Chen, Chao
author_facet Pourayoubi, Mehrdad
Yousefi, Mohammad
Eslami, Farnaz
Rheingold, Arnold L.
Chen, Chao
author_sort Pourayoubi, Mehrdad
collection PubMed
description In the title compound, C(14)H(18)N(3)OP, a crystallographic mirror plane bis­ects the mol­ecule (the C,N,C atoms of the dimethyl­amido moiety and the P=O unit lie on the mirror plane). The P atom has a distorted tetra­hedral geometry; the bond angles at P are in the range 98.98 (11)–115.28 (7)°. In the crystal, the O atom of the P=O group acts as a double hydrogen-bond acceptor for two symmetry-equivalent N—H⋯O hydrogen bonds, building [001] chains containing R (2) (1)(6) loops.
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spelling pubmed-32388822011-12-23 N,N-Dimethyl-N′,N′′-diphenyl­phospho­ric triamide Pourayoubi, Mehrdad Yousefi, Mohammad Eslami, Farnaz Rheingold, Arnold L. Chen, Chao Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(18)N(3)OP, a crystallographic mirror plane bis­ects the mol­ecule (the C,N,C atoms of the dimethyl­amido moiety and the P=O unit lie on the mirror plane). The P atom has a distorted tetra­hedral geometry; the bond angles at P are in the range 98.98 (11)–115.28 (7)°. In the crystal, the O atom of the P=O group acts as a double hydrogen-bond acceptor for two symmetry-equivalent N—H⋯O hydrogen bonds, building [001] chains containing R (2) (1)(6) loops. International Union of Crystallography 2011-11-09 /pmc/articles/PMC3238882/ /pubmed/22199735 http://dx.doi.org/10.1107/S1600536811046058 Text en © Pourayoubi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pourayoubi, Mehrdad
Yousefi, Mohammad
Eslami, Farnaz
Rheingold, Arnold L.
Chen, Chao
N,N-Dimethyl-N′,N′′-diphenyl­phospho­ric triamide
title N,N-Dimethyl-N′,N′′-diphenyl­phospho­ric triamide
title_full N,N-Dimethyl-N′,N′′-diphenyl­phospho­ric triamide
title_fullStr N,N-Dimethyl-N′,N′′-diphenyl­phospho­ric triamide
title_full_unstemmed N,N-Dimethyl-N′,N′′-diphenyl­phospho­ric triamide
title_short N,N-Dimethyl-N′,N′′-diphenyl­phospho­ric triamide
title_sort n,n-dimethyl-n′,n′′-diphenyl­phospho­ric triamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238882/
https://www.ncbi.nlm.nih.gov/pubmed/22199735
http://dx.doi.org/10.1107/S1600536811046058
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