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N,N′-Dibenzyl-N,N′-dimethyl-N′′-(p-tol­yl)phospho­ric triamide

The asymmetric unit of the title compound, C(23)H(28)N(3)OP, contains two independent mol­ecules with significant conformational differences. For example, the torsion angles N—C—C—C involving the N-benzyl moieties are 57.3 (7) and 11.6 (8)° in one mol­ecule and 76.5 (7) and 97.4 (7)° in the other. I...

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Detalles Bibliográficos
Autores principales: Pourayoubi, Mehrdad, Elahi, Behrouz, Parvez, Masood
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238883/
https://www.ncbi.nlm.nih.gov/pubmed/22199736
http://dx.doi.org/10.1107/S1600536811046046
Descripción
Sumario:The asymmetric unit of the title compound, C(23)H(28)N(3)OP, contains two independent mol­ecules with significant conformational differences. For example, the torsion angles N—C—C—C involving the N-benzyl moieties are 57.3 (7) and 11.6 (8)° in one mol­ecule and 76.5 (7) and 97.4 (7)° in the other. In each mol­ecule, the P atom exhibits a distorted tetra­hedral conformation [the bond angles at P are in the ranges 104.7 (2)–115.2 (2) and 105.1 (2)–115.1 (2)° in the two molecules], and the phosphoryl group and the N—H group adopt an anti orientation with respect to one another. In the crystal, mol­ecules are linked via N—H⋯O(P) hydrogen bonds, forming a chain parallel to the a axis.