N,N′-Dibenzyl-N,N′-dimethyl-N′′-(p-tol­yl)phospho­ric triamide

The asymmetric unit of the title compound, C(23)H(28)N(3)OP, contains two independent mol­ecules with significant conformational differences. For example, the torsion angles N—C—C—C involving the N-benzyl moieties are 57.3 (7) and 11.6 (8)° in one mol­ecule and 76.5 (7) and 97.4 (7)° in the other. I...

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Detalles Bibliográficos
Autores principales: Pourayoubi, Mehrdad, Elahi, Behrouz, Parvez, Masood
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238883/
https://www.ncbi.nlm.nih.gov/pubmed/22199736
http://dx.doi.org/10.1107/S1600536811046046
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author Pourayoubi, Mehrdad
Elahi, Behrouz
Parvez, Masood
author_facet Pourayoubi, Mehrdad
Elahi, Behrouz
Parvez, Masood
author_sort Pourayoubi, Mehrdad
collection PubMed
description The asymmetric unit of the title compound, C(23)H(28)N(3)OP, contains two independent mol­ecules with significant conformational differences. For example, the torsion angles N—C—C—C involving the N-benzyl moieties are 57.3 (7) and 11.6 (8)° in one mol­ecule and 76.5 (7) and 97.4 (7)° in the other. In each mol­ecule, the P atom exhibits a distorted tetra­hedral conformation [the bond angles at P are in the ranges 104.7 (2)–115.2 (2) and 105.1 (2)–115.1 (2)° in the two molecules], and the phosphoryl group and the N—H group adopt an anti orientation with respect to one another. In the crystal, mol­ecules are linked via N—H⋯O(P) hydrogen bonds, forming a chain parallel to the a axis.
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spelling pubmed-32388832011-12-23 N,N′-Dibenzyl-N,N′-dimethyl-N′′-(p-tol­yl)phospho­ric triamide Pourayoubi, Mehrdad Elahi, Behrouz Parvez, Masood Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(23)H(28)N(3)OP, contains two independent mol­ecules with significant conformational differences. For example, the torsion angles N—C—C—C involving the N-benzyl moieties are 57.3 (7) and 11.6 (8)° in one mol­ecule and 76.5 (7) and 97.4 (7)° in the other. In each mol­ecule, the P atom exhibits a distorted tetra­hedral conformation [the bond angles at P are in the ranges 104.7 (2)–115.2 (2) and 105.1 (2)–115.1 (2)° in the two molecules], and the phosphoryl group and the N—H group adopt an anti orientation with respect to one another. In the crystal, mol­ecules are linked via N—H⋯O(P) hydrogen bonds, forming a chain parallel to the a axis. International Union of Crystallography 2011-11-09 /pmc/articles/PMC3238883/ /pubmed/22199736 http://dx.doi.org/10.1107/S1600536811046046 Text en © Pourayoubi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pourayoubi, Mehrdad
Elahi, Behrouz
Parvez, Masood
N,N′-Dibenzyl-N,N′-dimethyl-N′′-(p-tol­yl)phospho­ric triamide
title N,N′-Dibenzyl-N,N′-dimethyl-N′′-(p-tol­yl)phospho­ric triamide
title_full N,N′-Dibenzyl-N,N′-dimethyl-N′′-(p-tol­yl)phospho­ric triamide
title_fullStr N,N′-Dibenzyl-N,N′-dimethyl-N′′-(p-tol­yl)phospho­ric triamide
title_full_unstemmed N,N′-Dibenzyl-N,N′-dimethyl-N′′-(p-tol­yl)phospho­ric triamide
title_short N,N′-Dibenzyl-N,N′-dimethyl-N′′-(p-tol­yl)phospho­ric triamide
title_sort n,n′-dibenzyl-n,n′-dimethyl-n′′-(p-tol­yl)phospho­ric triamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238883/
https://www.ncbi.nlm.nih.gov/pubmed/22199736
http://dx.doi.org/10.1107/S1600536811046046
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