(E)-1-([1,1′-Biphen­yl]-4-yl)-2-(1,3,3-tri­methylindolin-2-yl­idene)ethanone

The title compound, C(25)H(23)NO, consists of a biphenyl-4-carbonyl unit attached to an exocyclic double bond group at position 2 of an indole unit, which presents methyl groups as substituents at positions 1 and 3. The mol­ecular conformation is s-cis with an E configuration, supported by weak intr...

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Autores principales: Vázquez-Vuelvas, Oscar F., Pineda-Contreras, Armando, Morales-Morales, David, Hernández-Ortega, Simón, Tlenkopatchev, Mikhail
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238885/
https://www.ncbi.nlm.nih.gov/pubmed/22199738
http://dx.doi.org/10.1107/S1600536811045168
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author Vázquez-Vuelvas, Oscar F.
Pineda-Contreras, Armando
Morales-Morales, David
Hernández-Ortega, Simón
Tlenkopatchev, Mikhail
author_facet Vázquez-Vuelvas, Oscar F.
Pineda-Contreras, Armando
Morales-Morales, David
Hernández-Ortega, Simón
Tlenkopatchev, Mikhail
author_sort Vázquez-Vuelvas, Oscar F.
collection PubMed
description The title compound, C(25)H(23)NO, consists of a biphenyl-4-carbonyl unit attached to an exocyclic double bond group at position 2 of an indole unit, which presents methyl groups as substituents at positions 1 and 3. The mol­ecular conformation is s-cis with an E configuration, supported by weak intra­molecular C—H⋯O contacts involving the methyl groups and the carbonyl function. The rings of the biphenyl group are twisted by 37.13 (5)°. In the crystal, C—H⋯O and C—H⋯π inter­actions link the molecules.
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spelling pubmed-32388852011-12-23 (E)-1-([1,1′-Biphen­yl]-4-yl)-2-(1,3,3-tri­methylindolin-2-yl­idene)ethanone Vázquez-Vuelvas, Oscar F. Pineda-Contreras, Armando Morales-Morales, David Hernández-Ortega, Simón Tlenkopatchev, Mikhail Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(25)H(23)NO, consists of a biphenyl-4-carbonyl unit attached to an exocyclic double bond group at position 2 of an indole unit, which presents methyl groups as substituents at positions 1 and 3. The mol­ecular conformation is s-cis with an E configuration, supported by weak intra­molecular C—H⋯O contacts involving the methyl groups and the carbonyl function. The rings of the biphenyl group are twisted by 37.13 (5)°. In the crystal, C—H⋯O and C—H⋯π inter­actions link the molecules. International Union of Crystallography 2011-11-09 /pmc/articles/PMC3238885/ /pubmed/22199738 http://dx.doi.org/10.1107/S1600536811045168 Text en © Vázquez-Vuelvas et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Vázquez-Vuelvas, Oscar F.
Pineda-Contreras, Armando
Morales-Morales, David
Hernández-Ortega, Simón
Tlenkopatchev, Mikhail
(E)-1-([1,1′-Biphen­yl]-4-yl)-2-(1,3,3-tri­methylindolin-2-yl­idene)ethanone
title (E)-1-([1,1′-Biphen­yl]-4-yl)-2-(1,3,3-tri­methylindolin-2-yl­idene)ethanone
title_full (E)-1-([1,1′-Biphen­yl]-4-yl)-2-(1,3,3-tri­methylindolin-2-yl­idene)ethanone
title_fullStr (E)-1-([1,1′-Biphen­yl]-4-yl)-2-(1,3,3-tri­methylindolin-2-yl­idene)ethanone
title_full_unstemmed (E)-1-([1,1′-Biphen­yl]-4-yl)-2-(1,3,3-tri­methylindolin-2-yl­idene)ethanone
title_short (E)-1-([1,1′-Biphen­yl]-4-yl)-2-(1,3,3-tri­methylindolin-2-yl­idene)ethanone
title_sort (e)-1-([1,1′-biphen­yl]-4-yl)-2-(1,3,3-tri­methylindolin-2-yl­idene)ethanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238885/
https://www.ncbi.nlm.nih.gov/pubmed/22199738
http://dx.doi.org/10.1107/S1600536811045168
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