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(E)-N′-(2,3-Dihy­droxy­benzyl­idene)-4-meth­oxy­benzohydrazide

The mol­ecule of the title benzohydrazide derivative, C(15)H(14)N(2)O(4), is twisted and exists in a trans conformation with respect to the C=N double bond. The dihedral angle between the benzene rings is 56.86 (9)° and the C atom of the meth­oxy group deviates slightly [C—O—C—C = −10.4 (3)°] from i...

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Autores principales: Promdet, Premrudee, Horkaew, Jirapa, Chantrapromma, Suchada, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238886/
https://www.ncbi.nlm.nih.gov/pubmed/22199739
http://dx.doi.org/10.1107/S1600536811045740
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author Promdet, Premrudee
Horkaew, Jirapa
Chantrapromma, Suchada
Fun, Hoong-Kun
author_facet Promdet, Premrudee
Horkaew, Jirapa
Chantrapromma, Suchada
Fun, Hoong-Kun
author_sort Promdet, Premrudee
collection PubMed
description The mol­ecule of the title benzohydrazide derivative, C(15)H(14)N(2)O(4), is twisted and exists in a trans conformation with respect to the C=N double bond. The dihedral angle between the benzene rings is 56.86 (9)° and the C atom of the meth­oxy group deviates slightly [C—O—C—C = −10.4 (3)°] from its attached benzene ring. An intra­molecular O—H⋯N hydrogen bond generates an S(6) ring. In the crystal, mol­ecules are linked by N—H⋯O and bifurcated N—H⋯(O,O) hydrogen bonds, as well as weak C—H⋯O inter­actions, into two-dimensional networks lying parallel to the bc plane. A weak C—H⋯π inter­action also occurs.
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spelling pubmed-32388862011-12-23 (E)-N′-(2,3-Dihy­droxy­benzyl­idene)-4-meth­oxy­benzohydrazide Promdet, Premrudee Horkaew, Jirapa Chantrapromma, Suchada Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title benzohydrazide derivative, C(15)H(14)N(2)O(4), is twisted and exists in a trans conformation with respect to the C=N double bond. The dihedral angle between the benzene rings is 56.86 (9)° and the C atom of the meth­oxy group deviates slightly [C—O—C—C = −10.4 (3)°] from its attached benzene ring. An intra­molecular O—H⋯N hydrogen bond generates an S(6) ring. In the crystal, mol­ecules are linked by N—H⋯O and bifurcated N—H⋯(O,O) hydrogen bonds, as well as weak C—H⋯O inter­actions, into two-dimensional networks lying parallel to the bc plane. A weak C—H⋯π inter­action also occurs. International Union of Crystallography 2011-11-12 /pmc/articles/PMC3238886/ /pubmed/22199739 http://dx.doi.org/10.1107/S1600536811045740 Text en © Promdet et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Promdet, Premrudee
Horkaew, Jirapa
Chantrapromma, Suchada
Fun, Hoong-Kun
(E)-N′-(2,3-Dihy­droxy­benzyl­idene)-4-meth­oxy­benzohydrazide
title (E)-N′-(2,3-Dihy­droxy­benzyl­idene)-4-meth­oxy­benzohydrazide
title_full (E)-N′-(2,3-Dihy­droxy­benzyl­idene)-4-meth­oxy­benzohydrazide
title_fullStr (E)-N′-(2,3-Dihy­droxy­benzyl­idene)-4-meth­oxy­benzohydrazide
title_full_unstemmed (E)-N′-(2,3-Dihy­droxy­benzyl­idene)-4-meth­oxy­benzohydrazide
title_short (E)-N′-(2,3-Dihy­droxy­benzyl­idene)-4-meth­oxy­benzohydrazide
title_sort (e)-n′-(2,3-dihy­droxy­benzyl­idene)-4-meth­oxy­benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238886/
https://www.ncbi.nlm.nih.gov/pubmed/22199739
http://dx.doi.org/10.1107/S1600536811045740
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