Ethyl 1-(butan-2-yl)-2-(2-meth­oxy­phen­yl)-1H-benzimidazole-5-carboxyl­ate

In the title compound, C(21)H(24)N(2)O(3), the mean planes of the benzene ring and the benzimidazole ring system form a dihedral angle of 69.94 (7)°. The ethyl group atoms of the ethano­ate fragment are disordered over two sets of sites, with refined occupancies of 0.742 (6) and 0.258 (6). In the cr...

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Detalles Bibliográficos
Autores principales: Arumugam, Natarajan, Ngah, Nurziana, Osman, Hasnah, Abdul Rahim, Aisyah Saad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238892/
https://www.ncbi.nlm.nih.gov/pubmed/22199745
http://dx.doi.org/10.1107/S1600536811046095
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author Arumugam, Natarajan
Ngah, Nurziana
Osman, Hasnah
Abdul Rahim, Aisyah Saad
author_facet Arumugam, Natarajan
Ngah, Nurziana
Osman, Hasnah
Abdul Rahim, Aisyah Saad
author_sort Arumugam, Natarajan
collection PubMed
description In the title compound, C(21)H(24)N(2)O(3), the mean planes of the benzene ring and the benzimidazole ring system form a dihedral angle of 69.94 (7)°. The ethyl group atoms of the ethano­ate fragment are disordered over two sets of sites, with refined occupancies of 0.742 (6) and 0.258 (6). In the crystal, there are weak C—H⋯N hydrogen bonds which connect mol­ecules into chains along the b axis. A weak inter­molecular C—H⋯π inter­action is also observed.
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spelling pubmed-32388922011-12-23 Ethyl 1-(butan-2-yl)-2-(2-meth­oxy­phen­yl)-1H-benzimidazole-5-carboxyl­ate Arumugam, Natarajan Ngah, Nurziana Osman, Hasnah Abdul Rahim, Aisyah Saad Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(24)N(2)O(3), the mean planes of the benzene ring and the benzimidazole ring system form a dihedral angle of 69.94 (7)°. The ethyl group atoms of the ethano­ate fragment are disordered over two sets of sites, with refined occupancies of 0.742 (6) and 0.258 (6). In the crystal, there are weak C—H⋯N hydrogen bonds which connect mol­ecules into chains along the b axis. A weak inter­molecular C—H⋯π inter­action is also observed. International Union of Crystallography 2011-11-09 /pmc/articles/PMC3238892/ /pubmed/22199745 http://dx.doi.org/10.1107/S1600536811046095 Text en © Arumugam et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Arumugam, Natarajan
Ngah, Nurziana
Osman, Hasnah
Abdul Rahim, Aisyah Saad
Ethyl 1-(butan-2-yl)-2-(2-meth­oxy­phen­yl)-1H-benzimidazole-5-carboxyl­ate
title Ethyl 1-(butan-2-yl)-2-(2-meth­oxy­phen­yl)-1H-benzimidazole-5-carboxyl­ate
title_full Ethyl 1-(butan-2-yl)-2-(2-meth­oxy­phen­yl)-1H-benzimidazole-5-carboxyl­ate
title_fullStr Ethyl 1-(butan-2-yl)-2-(2-meth­oxy­phen­yl)-1H-benzimidazole-5-carboxyl­ate
title_full_unstemmed Ethyl 1-(butan-2-yl)-2-(2-meth­oxy­phen­yl)-1H-benzimidazole-5-carboxyl­ate
title_short Ethyl 1-(butan-2-yl)-2-(2-meth­oxy­phen­yl)-1H-benzimidazole-5-carboxyl­ate
title_sort ethyl 1-(butan-2-yl)-2-(2-meth­oxy­phen­yl)-1h-benzimidazole-5-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238892/
https://www.ncbi.nlm.nih.gov/pubmed/22199745
http://dx.doi.org/10.1107/S1600536811046095
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AT osmanhasnah ethyl1butan2yl22methoxyphenyl1hbenzimidazole5carboxylate
AT abdulrahimaisyahsaad ethyl1butan2yl22methoxyphenyl1hbenzimidazole5carboxylate

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