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N,N′-Bis(2-aminobenzyl)ethane-1,2-diaminium bis(4-methylbenzenesulfonate)
The title salt, C(16)H(24)N(4) (2+)·2C(7)H(7)O(3)S(−), crystallizes with the dication situated on an inversion center and the anion in a general position. The cation contains two ammonium and two free amine groups, and the observed conformation for the chain linking the benzene rings is different fr...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238895/ https://www.ncbi.nlm.nih.gov/pubmed/22199748 http://dx.doi.org/10.1107/S1600536811045879 |
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author | Garza Rodríguez, Luis Ángel Bernès, Sylvain Elizondo Martínez, Perla Nájera Martínez, Blanca Rodríguez de Luna, Sara L. |
author_facet | Garza Rodríguez, Luis Ángel Bernès, Sylvain Elizondo Martínez, Perla Nájera Martínez, Blanca Rodríguez de Luna, Sara L. |
author_sort | Garza Rodríguez, Luis Ángel |
collection | PubMed |
description | The title salt, C(16)H(24)N(4) (2+)·2C(7)H(7)O(3)S(−), crystallizes with the dication situated on an inversion center and the anion in a general position. The cation contains two ammonium and two free amine groups, and the observed conformation for the chain linking the benzene rings is different from that found in the free tetraamine and in the fully protonated tetraamine. All amine and ammonium H atoms of the cation form hydrogen bonds with eight symmetry-related anions, using the sulfonate O atoms as acceptors. This arrangement for the ions precludes any π–π contacts between benzene rings in the crystal. |
format | Online Article Text |
id | pubmed-3238895 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32388952011-12-23 N,N′-Bis(2-aminobenzyl)ethane-1,2-diaminium bis(4-methylbenzenesulfonate) Garza Rodríguez, Luis Ángel Bernès, Sylvain Elizondo Martínez, Perla Nájera Martínez, Blanca Rodríguez de Luna, Sara L. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title salt, C(16)H(24)N(4) (2+)·2C(7)H(7)O(3)S(−), crystallizes with the dication situated on an inversion center and the anion in a general position. The cation contains two ammonium and two free amine groups, and the observed conformation for the chain linking the benzene rings is different from that found in the free tetraamine and in the fully protonated tetraamine. All amine and ammonium H atoms of the cation form hydrogen bonds with eight symmetry-related anions, using the sulfonate O atoms as acceptors. This arrangement for the ions precludes any π–π contacts between benzene rings in the crystal. International Union of Crystallography 2011-11-09 /pmc/articles/PMC3238895/ /pubmed/22199748 http://dx.doi.org/10.1107/S1600536811045879 Text en © Garza Rodríguez et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Garza Rodríguez, Luis Ángel Bernès, Sylvain Elizondo Martínez, Perla Nájera Martínez, Blanca Rodríguez de Luna, Sara L. N,N′-Bis(2-aminobenzyl)ethane-1,2-diaminium bis(4-methylbenzenesulfonate) |
title |
N,N′-Bis(2-aminobenzyl)ethane-1,2-diaminium bis(4-methylbenzenesulfonate) |
title_full |
N,N′-Bis(2-aminobenzyl)ethane-1,2-diaminium bis(4-methylbenzenesulfonate) |
title_fullStr |
N,N′-Bis(2-aminobenzyl)ethane-1,2-diaminium bis(4-methylbenzenesulfonate) |
title_full_unstemmed |
N,N′-Bis(2-aminobenzyl)ethane-1,2-diaminium bis(4-methylbenzenesulfonate) |
title_short |
N,N′-Bis(2-aminobenzyl)ethane-1,2-diaminium bis(4-methylbenzenesulfonate) |
title_sort | n,n′-bis(2-aminobenzyl)ethane-1,2-diaminium bis(4-methylbenzenesulfonate) |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238895/ https://www.ncbi.nlm.nih.gov/pubmed/22199748 http://dx.doi.org/10.1107/S1600536811045879 |
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