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N,N′-Bis(2-amino­benz­yl)ethane-1,2-diaminium bis­(4-methyl­benzene­sulfonate)

The title salt, C(16)H(24)N(4) (2+)·2C(7)H(7)O(3)S(−), crystallizes with the dication situated on an inversion center and the anion in a general position. The cation contains two ammonium and two free amine groups, and the observed conformation for the chain linking the benzene rings is different fr...

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Autores principales: Garza Rodríguez, Luis Ángel, Bernès, Sylvain, Elizondo Martínez, Perla, Nájera Martínez, Blanca, Rodríguez de Luna, Sara L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238895/
https://www.ncbi.nlm.nih.gov/pubmed/22199748
http://dx.doi.org/10.1107/S1600536811045879
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author Garza Rodríguez, Luis Ángel
Bernès, Sylvain
Elizondo Martínez, Perla
Nájera Martínez, Blanca
Rodríguez de Luna, Sara L.
author_facet Garza Rodríguez, Luis Ángel
Bernès, Sylvain
Elizondo Martínez, Perla
Nájera Martínez, Blanca
Rodríguez de Luna, Sara L.
author_sort Garza Rodríguez, Luis Ángel
collection PubMed
description The title salt, C(16)H(24)N(4) (2+)·2C(7)H(7)O(3)S(−), crystallizes with the dication situated on an inversion center and the anion in a general position. The cation contains two ammonium and two free amine groups, and the observed conformation for the chain linking the benzene rings is different from that found in the free tetra­amine and in the fully protonated tetra­amine. All amine and ammonium H atoms of the cation form hydrogen bonds with eight symmetry-related anions, using the sulfonate O atoms as acceptors. This arrangement for the ions precludes any π–π contacts between benzene rings in the crystal.
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spelling pubmed-32388952011-12-23 N,N′-Bis(2-amino­benz­yl)ethane-1,2-diaminium bis­(4-methyl­benzene­sulfonate) Garza Rodríguez, Luis Ángel Bernès, Sylvain Elizondo Martínez, Perla Nájera Martínez, Blanca Rodríguez de Luna, Sara L. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title salt, C(16)H(24)N(4) (2+)·2C(7)H(7)O(3)S(−), crystallizes with the dication situated on an inversion center and the anion in a general position. The cation contains two ammonium and two free amine groups, and the observed conformation for the chain linking the benzene rings is different from that found in the free tetra­amine and in the fully protonated tetra­amine. All amine and ammonium H atoms of the cation form hydrogen bonds with eight symmetry-related anions, using the sulfonate O atoms as acceptors. This arrangement for the ions precludes any π–π contacts between benzene rings in the crystal. International Union of Crystallography 2011-11-09 /pmc/articles/PMC3238895/ /pubmed/22199748 http://dx.doi.org/10.1107/S1600536811045879 Text en © Garza Rodríguez et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Garza Rodríguez, Luis Ángel
Bernès, Sylvain
Elizondo Martínez, Perla
Nájera Martínez, Blanca
Rodríguez de Luna, Sara L.
N,N′-Bis(2-amino­benz­yl)ethane-1,2-diaminium bis­(4-methyl­benzene­sulfonate)
title N,N′-Bis(2-amino­benz­yl)ethane-1,2-diaminium bis­(4-methyl­benzene­sulfonate)
title_full N,N′-Bis(2-amino­benz­yl)ethane-1,2-diaminium bis­(4-methyl­benzene­sulfonate)
title_fullStr N,N′-Bis(2-amino­benz­yl)ethane-1,2-diaminium bis­(4-methyl­benzene­sulfonate)
title_full_unstemmed N,N′-Bis(2-amino­benz­yl)ethane-1,2-diaminium bis­(4-methyl­benzene­sulfonate)
title_short N,N′-Bis(2-amino­benz­yl)ethane-1,2-diaminium bis­(4-methyl­benzene­sulfonate)
title_sort n,n′-bis(2-amino­benz­yl)ethane-1,2-diaminium bis­(4-methyl­benzene­sulfonate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238895/
https://www.ncbi.nlm.nih.gov/pubmed/22199748
http://dx.doi.org/10.1107/S1600536811045879
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