5-(4-Chloro­phen­oxy)-1-methyl-3-tri­fluoro­methyl-1H-pyrazole-4-carbaldehyde O-[(2-chloro­pyridin-5-yl)meth­yl]oxime

In the title mol­ecule, C(18)H(13)Cl(2)F(3)N(4)O(2), the intra­molecular distance between the centroids of the benzene and pyridine rings is 3.953 (3) Å, and the trifluoro­methyl group is rotationally disordered over two orientations in a 0.678 (19):0.322 (19) ratio. The crystal packing exhibits wea...

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Detalles Bibliográficos
Autores principales: Dai, Hong, Zhu, Peng-Fei, Zhu, Yu-Jun, Fang, Jian-Xin, Shi, Yu-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238903/
https://www.ncbi.nlm.nih.gov/pubmed/22199756
http://dx.doi.org/10.1107/S1600536811046459
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author Dai, Hong
Zhu, Peng-Fei
Zhu, Yu-Jun
Fang, Jian-Xin
Shi, Yu-Jun
author_facet Dai, Hong
Zhu, Peng-Fei
Zhu, Yu-Jun
Fang, Jian-Xin
Shi, Yu-Jun
author_sort Dai, Hong
collection PubMed
description In the title mol­ecule, C(18)H(13)Cl(2)F(3)N(4)O(2), the intra­molecular distance between the centroids of the benzene and pyridine rings is 3.953 (3) Å, and the trifluoro­methyl group is rotationally disordered over two orientations in a 0.678 (19):0.322 (19) ratio. The crystal packing exhibits weak inter­molecular C—H⋯F inter­actions.
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spelling pubmed-32389032011-12-23 5-(4-Chloro­phen­oxy)-1-methyl-3-tri­fluoro­methyl-1H-pyrazole-4-carbaldehyde O-[(2-chloro­pyridin-5-yl)meth­yl]oxime Dai, Hong Zhu, Peng-Fei Zhu, Yu-Jun Fang, Jian-Xin Shi, Yu-Jun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(18)H(13)Cl(2)F(3)N(4)O(2), the intra­molecular distance between the centroids of the benzene and pyridine rings is 3.953 (3) Å, and the trifluoro­methyl group is rotationally disordered over two orientations in a 0.678 (19):0.322 (19) ratio. The crystal packing exhibits weak inter­molecular C—H⋯F inter­actions. International Union of Crystallography 2011-11-09 /pmc/articles/PMC3238903/ /pubmed/22199756 http://dx.doi.org/10.1107/S1600536811046459 Text en © Dai et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Dai, Hong
Zhu, Peng-Fei
Zhu, Yu-Jun
Fang, Jian-Xin
Shi, Yu-Jun
5-(4-Chloro­phen­oxy)-1-methyl-3-tri­fluoro­methyl-1H-pyrazole-4-carbaldehyde O-[(2-chloro­pyridin-5-yl)meth­yl]oxime
title 5-(4-Chloro­phen­oxy)-1-methyl-3-tri­fluoro­methyl-1H-pyrazole-4-carbaldehyde O-[(2-chloro­pyridin-5-yl)meth­yl]oxime
title_full 5-(4-Chloro­phen­oxy)-1-methyl-3-tri­fluoro­methyl-1H-pyrazole-4-carbaldehyde O-[(2-chloro­pyridin-5-yl)meth­yl]oxime
title_fullStr 5-(4-Chloro­phen­oxy)-1-methyl-3-tri­fluoro­methyl-1H-pyrazole-4-carbaldehyde O-[(2-chloro­pyridin-5-yl)meth­yl]oxime
title_full_unstemmed 5-(4-Chloro­phen­oxy)-1-methyl-3-tri­fluoro­methyl-1H-pyrazole-4-carbaldehyde O-[(2-chloro­pyridin-5-yl)meth­yl]oxime
title_short 5-(4-Chloro­phen­oxy)-1-methyl-3-tri­fluoro­methyl-1H-pyrazole-4-carbaldehyde O-[(2-chloro­pyridin-5-yl)meth­yl]oxime
title_sort 5-(4-chloro­phen­oxy)-1-methyl-3-tri­fluoro­methyl-1h-pyrazole-4-carbaldehyde o-[(2-chloro­pyridin-5-yl)meth­yl]oxime
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238903/
https://www.ncbi.nlm.nih.gov/pubmed/22199756
http://dx.doi.org/10.1107/S1600536811046459
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