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2-{[(4-{[(2-Hydroxyphenyl)(phenyl)methylidene]amino}phenyl)imino](phenyl)methyl}phenol
The title molecule, C(32)H(24)N(2)O(2), has a crystallographically imposed inversion centre and exists in the crystal as an enol–imine tautomer. The molecular structure is stabilized by two strong intramolecular O—H⋯N hydrogen bonds. The dihedral angles between the central benzene ring and the me...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238908/ https://www.ncbi.nlm.nih.gov/pubmed/22199761 http://dx.doi.org/10.1107/S1600536811046988 |
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author | Blagus, Anita Kaitner, Branko |
author_facet | Blagus, Anita Kaitner, Branko |
author_sort | Blagus, Anita |
collection | PubMed |
description | The title molecule, C(32)H(24)N(2)O(2), has a crystallographically imposed inversion centre and exists in the crystal as an enol–imine tautomer. The molecular structure is stabilized by two strong intramolecular O—H⋯N hydrogen bonds. The dihedral angles between the central benzene ring and the mean planes of the phenyl substituents are 59.99 (1) and 62.79 (2)°. In the crystal, the molecules are arranged into (010) layers via C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-3238908 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32389082011-12-23 2-{[(4-{[(2-Hydroxyphenyl)(phenyl)methylidene]amino}phenyl)imino](phenyl)methyl}phenol Blagus, Anita Kaitner, Branko Acta Crystallogr Sect E Struct Rep Online Organic Papers The title molecule, C(32)H(24)N(2)O(2), has a crystallographically imposed inversion centre and exists in the crystal as an enol–imine tautomer. The molecular structure is stabilized by two strong intramolecular O—H⋯N hydrogen bonds. The dihedral angles between the central benzene ring and the mean planes of the phenyl substituents are 59.99 (1) and 62.79 (2)°. In the crystal, the molecules are arranged into (010) layers via C—H⋯π interactions. International Union of Crystallography 2011-11-09 /pmc/articles/PMC3238908/ /pubmed/22199761 http://dx.doi.org/10.1107/S1600536811046988 Text en © Blagus and Kaitner 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Blagus, Anita Kaitner, Branko 2-{[(4-{[(2-Hydroxyphenyl)(phenyl)methylidene]amino}phenyl)imino](phenyl)methyl}phenol |
title | 2-{[(4-{[(2-Hydroxyphenyl)(phenyl)methylidene]amino}phenyl)imino](phenyl)methyl}phenol |
title_full | 2-{[(4-{[(2-Hydroxyphenyl)(phenyl)methylidene]amino}phenyl)imino](phenyl)methyl}phenol |
title_fullStr | 2-{[(4-{[(2-Hydroxyphenyl)(phenyl)methylidene]amino}phenyl)imino](phenyl)methyl}phenol |
title_full_unstemmed | 2-{[(4-{[(2-Hydroxyphenyl)(phenyl)methylidene]amino}phenyl)imino](phenyl)methyl}phenol |
title_short | 2-{[(4-{[(2-Hydroxyphenyl)(phenyl)methylidene]amino}phenyl)imino](phenyl)methyl}phenol |
title_sort | 2-{[(4-{[(2-hydroxyphenyl)(phenyl)methylidene]amino}phenyl)imino](phenyl)methyl}phenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238908/ https://www.ncbi.nlm.nih.gov/pubmed/22199761 http://dx.doi.org/10.1107/S1600536811046988 |
work_keys_str_mv | AT blagusanita 242hydroxyphenylphenylmethylideneaminophenyliminophenylmethylphenol AT kaitnerbranko 242hydroxyphenylphenylmethylideneaminophenyliminophenylmethylphenol |