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4-Methyl-N′-(2-oxoindolin-3-ylidene)benzene-1-sulfonohydrazide
In the title compound, C(15)H(13)N(3)O(3)S, the C—S—N(H)—N linkage is non-planar, the torsion angle being −65.12 (13)° and the S atom showing a tetrahedral environment. The compound has two almost planar fragments linked to the S atom: the isatin-derivative fragment [(C(8)H(5)NO)N—N(H)–] and the to...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238916/ https://www.ncbi.nlm.nih.gov/pubmed/22199765 http://dx.doi.org/10.1107/S1600536811046605 |
Sumario: | In the title compound, C(15)H(13)N(3)O(3)S, the C—S—N(H)—N linkage is non-planar, the torsion angle being −65.12 (13)° and the S atom showing a tetrahedral environment. The compound has two almost planar fragments linked to the S atom: the isatin-derivative fragment [(C(8)H(5)NO)N—N(H)–] and the tolyl fragment [C(7)H(7)–] have maximum deviations from the mean plane through the non-H atoms of 0.0813 (13) and 0.0094 (16) Å, respectively, and make an interplanar angle of 80.48 (3)°. In the crystal, molecules are connected into inversion dimers via pairs of N—H⋯O hydrogen bonds. Additionally, the molecular structure is stabilized by an intramolecular N—H⋯O hydrogen bond. |
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