4-Methyl-N′-(2-oxoindolin-3-yl­idene)benzene-1-sulfono­hydrazide

In the title compound, C(15)H(13)N(3)O(3)S, the C—S—N(H)—N linkage is non-planar, the torsion angle being −65.12 (13)° and the S atom showing a tetra­hedral environment. The compound has two almost planar fragments linked to the S atom: the isatin-derivative fragment [(C(8)H(5)NO)N—N(H)–] and the to...

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Autores principales: Fonseca, Alexandra de Souza, Storino, Tomás Garcia, Carratu, Vanessa Santana, Locatelli, Aline, de Oliveira, Adriano Bof
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238916/
https://www.ncbi.nlm.nih.gov/pubmed/22199765
http://dx.doi.org/10.1107/S1600536811046605
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author Fonseca, Alexandra de Souza
Storino, Tomás Garcia
Carratu, Vanessa Santana
Locatelli, Aline
de Oliveira, Adriano Bof
author_facet Fonseca, Alexandra de Souza
Storino, Tomás Garcia
Carratu, Vanessa Santana
Locatelli, Aline
de Oliveira, Adriano Bof
author_sort Fonseca, Alexandra de Souza
collection PubMed
description In the title compound, C(15)H(13)N(3)O(3)S, the C—S—N(H)—N linkage is non-planar, the torsion angle being −65.12 (13)° and the S atom showing a tetra­hedral environment. The compound has two almost planar fragments linked to the S atom: the isatin-derivative fragment [(C(8)H(5)NO)N—N(H)–] and the tolyl fragment [C(7)H(7)–] have maximum deviations from the mean plane through the non-H atoms of 0.0813 (13) and 0.0094 (16) Å, respectively, and make an inter­planar angle of 80.48 (3)°. In the crystal, mol­ecules are connected into inversion dimers via pairs of N—H⋯O hydrogen bonds. Additionally, the mol­ecular structure is stabilized by an intra­molecular N—H⋯O hydrogen bond.
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spelling pubmed-32389162011-12-23 4-Methyl-N′-(2-oxoindolin-3-yl­idene)benzene-1-sulfono­hydrazide Fonseca, Alexandra de Souza Storino, Tomás Garcia Carratu, Vanessa Santana Locatelli, Aline de Oliveira, Adriano Bof Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(13)N(3)O(3)S, the C—S—N(H)—N linkage is non-planar, the torsion angle being −65.12 (13)° and the S atom showing a tetra­hedral environment. The compound has two almost planar fragments linked to the S atom: the isatin-derivative fragment [(C(8)H(5)NO)N—N(H)–] and the tolyl fragment [C(7)H(7)–] have maximum deviations from the mean plane through the non-H atoms of 0.0813 (13) and 0.0094 (16) Å, respectively, and make an inter­planar angle of 80.48 (3)°. In the crystal, mol­ecules are connected into inversion dimers via pairs of N—H⋯O hydrogen bonds. Additionally, the mol­ecular structure is stabilized by an intra­molecular N—H⋯O hydrogen bond. International Union of Crystallography 2011-11-12 /pmc/articles/PMC3238916/ /pubmed/22199765 http://dx.doi.org/10.1107/S1600536811046605 Text en © Fonseca et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fonseca, Alexandra de Souza
Storino, Tomás Garcia
Carratu, Vanessa Santana
Locatelli, Aline
de Oliveira, Adriano Bof
4-Methyl-N′-(2-oxoindolin-3-yl­idene)benzene-1-sulfono­hydrazide
title 4-Methyl-N′-(2-oxoindolin-3-yl­idene)benzene-1-sulfono­hydrazide
title_full 4-Methyl-N′-(2-oxoindolin-3-yl­idene)benzene-1-sulfono­hydrazide
title_fullStr 4-Methyl-N′-(2-oxoindolin-3-yl­idene)benzene-1-sulfono­hydrazide
title_full_unstemmed 4-Methyl-N′-(2-oxoindolin-3-yl­idene)benzene-1-sulfono­hydrazide
title_short 4-Methyl-N′-(2-oxoindolin-3-yl­idene)benzene-1-sulfono­hydrazide
title_sort 4-methyl-n′-(2-oxoindolin-3-yl­idene)benzene-1-sulfono­hydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238916/
https://www.ncbi.nlm.nih.gov/pubmed/22199765
http://dx.doi.org/10.1107/S1600536811046605
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