N′-[(E)-Furan-2-yl­methyl­idene]pyridine-3-carbohydrazide

The title compound, C(11)H(9)N(3)O(2), exists in the E conformation with respect to the azomethane C=N bond, and has the keto form. There are two independent mol­ecules in the asymmetric unit and each of these features a slight slanting of the pyridine and furan rings, which form a dihedral angle of...

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Detalles Bibliográficos
Autores principales: Emmanuel, Jessy, Sithambaresan, M., Kurup, M. R. Prathapachandra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238925/
https://www.ncbi.nlm.nih.gov/pubmed/22199774
http://dx.doi.org/10.1107/S1600536811046381
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author Emmanuel, Jessy
Sithambaresan, M.
Kurup, M. R. Prathapachandra
author_facet Emmanuel, Jessy
Sithambaresan, M.
Kurup, M. R. Prathapachandra
author_sort Emmanuel, Jessy
collection PubMed
description The title compound, C(11)H(9)N(3)O(2), exists in the E conformation with respect to the azomethane C=N bond, and has the keto form. There are two independent mol­ecules in the asymmetric unit and each of these features a slight slanting of the pyridine and furan rings, which form a dihedral angle of 14.96 (10)° in one of the mol­ecules and 5.53 (10)° in the other. The crystal structure is stabilized by N—H⋯O and N—H⋯N hydrogen bonds, weak C—H⋯O and C—H⋯N hydrogen bonds and C—H⋯π inter­actions and π–π inter­actions [shortest centroid–centroid distance = 3.7864 (15) Å].
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spelling pubmed-32389252011-12-23 N′-[(E)-Furan-2-yl­methyl­idene]pyridine-3-carbohydrazide Emmanuel, Jessy Sithambaresan, M. Kurup, M. R. Prathapachandra Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(11)H(9)N(3)O(2), exists in the E conformation with respect to the azomethane C=N bond, and has the keto form. There are two independent mol­ecules in the asymmetric unit and each of these features a slight slanting of the pyridine and furan rings, which form a dihedral angle of 14.96 (10)° in one of the mol­ecules and 5.53 (10)° in the other. The crystal structure is stabilized by N—H⋯O and N—H⋯N hydrogen bonds, weak C—H⋯O and C—H⋯N hydrogen bonds and C—H⋯π inter­actions and π–π inter­actions [shortest centroid–centroid distance = 3.7864 (15) Å]. International Union of Crystallography 2011-11-12 /pmc/articles/PMC3238925/ /pubmed/22199774 http://dx.doi.org/10.1107/S1600536811046381 Text en © Emmanuel et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Emmanuel, Jessy
Sithambaresan, M.
Kurup, M. R. Prathapachandra
N′-[(E)-Furan-2-yl­methyl­idene]pyridine-3-carbohydrazide
title N′-[(E)-Furan-2-yl­methyl­idene]pyridine-3-carbohydrazide
title_full N′-[(E)-Furan-2-yl­methyl­idene]pyridine-3-carbohydrazide
title_fullStr N′-[(E)-Furan-2-yl­methyl­idene]pyridine-3-carbohydrazide
title_full_unstemmed N′-[(E)-Furan-2-yl­methyl­idene]pyridine-3-carbohydrazide
title_short N′-[(E)-Furan-2-yl­methyl­idene]pyridine-3-carbohydrazide
title_sort n′-[(e)-furan-2-yl­methyl­idene]pyridine-3-carbohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238925/
https://www.ncbi.nlm.nih.gov/pubmed/22199774
http://dx.doi.org/10.1107/S1600536811046381
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