2-(6-Chloro-2,3,4,9-tetra­hydro-1H-carbazol-1-yl­idene)propane­dinitrile

The mol­ecular conformation of the title compound, C(15)H(10)ClN(3), is stabilized by an intra­molecular N—H⋯N hydrogen bond with an S(7) ring motif. The crystal packing is controlled by N—H⋯N and C—H⋯N inter­molecular inter­actions. One of the methyl­ene groups of the cyclo­hexene ring is disordere...

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Detalles Bibliográficos
Autores principales: Sekar, M., Velmurugan, R., Vijayasankar, A. V., Ramesh, P., Ponnuswamy, M. N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238926/
https://www.ncbi.nlm.nih.gov/pubmed/22199775
http://dx.doi.org/10.1107/S1600536811046575
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author Sekar, M.
Velmurugan, R.
Vijayasankar, A. V.
Ramesh, P.
Ponnuswamy, M. N.
author_facet Sekar, M.
Velmurugan, R.
Vijayasankar, A. V.
Ramesh, P.
Ponnuswamy, M. N.
author_sort Sekar, M.
collection PubMed
description The mol­ecular conformation of the title compound, C(15)H(10)ClN(3), is stabilized by an intra­molecular N—H⋯N hydrogen bond with an S(7) ring motif. The crystal packing is controlled by N—H⋯N and C—H⋯N inter­molecular inter­actions. One of the methyl­ene groups of the cyclo­hexene ring is disordered over two positions with refined occupancies of 0.457 (12) and 0.543 (12).
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spelling pubmed-32389262011-12-23 2-(6-Chloro-2,3,4,9-tetra­hydro-1H-carbazol-1-yl­idene)propane­dinitrile Sekar, M. Velmurugan, R. Vijayasankar, A. V. Ramesh, P. Ponnuswamy, M. N. Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecular conformation of the title compound, C(15)H(10)ClN(3), is stabilized by an intra­molecular N—H⋯N hydrogen bond with an S(7) ring motif. The crystal packing is controlled by N—H⋯N and C—H⋯N inter­molecular inter­actions. One of the methyl­ene groups of the cyclo­hexene ring is disordered over two positions with refined occupancies of 0.457 (12) and 0.543 (12). International Union of Crystallography 2011-11-12 /pmc/articles/PMC3238926/ /pubmed/22199775 http://dx.doi.org/10.1107/S1600536811046575 Text en © Sekar et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sekar, M.
Velmurugan, R.
Vijayasankar, A. V.
Ramesh, P.
Ponnuswamy, M. N.
2-(6-Chloro-2,3,4,9-tetra­hydro-1H-carbazol-1-yl­idene)propane­dinitrile
title 2-(6-Chloro-2,3,4,9-tetra­hydro-1H-carbazol-1-yl­idene)propane­dinitrile
title_full 2-(6-Chloro-2,3,4,9-tetra­hydro-1H-carbazol-1-yl­idene)propane­dinitrile
title_fullStr 2-(6-Chloro-2,3,4,9-tetra­hydro-1H-carbazol-1-yl­idene)propane­dinitrile
title_full_unstemmed 2-(6-Chloro-2,3,4,9-tetra­hydro-1H-carbazol-1-yl­idene)propane­dinitrile
title_short 2-(6-Chloro-2,3,4,9-tetra­hydro-1H-carbazol-1-yl­idene)propane­dinitrile
title_sort 2-(6-chloro-2,3,4,9-tetra­hydro-1h-carbazol-1-yl­idene)propane­dinitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238926/
https://www.ncbi.nlm.nih.gov/pubmed/22199775
http://dx.doi.org/10.1107/S1600536811046575
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AT vijayasankarav 26chloro2349tetrahydro1hcarbazol1ylidenepropanedinitrile
AT rameshp 26chloro2349tetrahydro1hcarbazol1ylidenepropanedinitrile
AT ponnuswamymn 26chloro2349tetrahydro1hcarbazol1ylidenepropanedinitrile

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