6-Bromo-2-[(E)-thio­phen-2-yl­methyl­idene]-2,3,4,9-tetra­hydro-1H-carbazol-1-one

In the title compound, C(17)H(12)BrNOS, the cyclo­hexene ring deviates only slightly from planarity (r.m.s. deviation for non-H atoms = 0.047 Å). In the crystal, the mol­ecules are linked into centro­symmetric R (2) (2)(10) dimers via pairs of N—H⋯O hydrogen bonds. The thio­phene ring is disordered...

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Autores principales: Velmurugan, R., Sekar, M., Vijayasankar, A. V., Ramesh, P., Ponnuswamy, M. N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238929/
https://www.ncbi.nlm.nih.gov/pubmed/22199778
http://dx.doi.org/10.1107/S1600536811046551
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author Velmurugan, R.
Sekar, M.
Vijayasankar, A. V.
Ramesh, P.
Ponnuswamy, M. N.
author_facet Velmurugan, R.
Sekar, M.
Vijayasankar, A. V.
Ramesh, P.
Ponnuswamy, M. N.
author_sort Velmurugan, R.
collection PubMed
description In the title compound, C(17)H(12)BrNOS, the cyclo­hexene ring deviates only slightly from planarity (r.m.s. deviation for non-H atoms = 0.047 Å). In the crystal, the mol­ecules are linked into centro­symmetric R (2) (2)(10) dimers via pairs of N—H⋯O hydrogen bonds. The thio­phene ring is disordered over two positions rotated by 180° and with a site-occupation factor of 0.843 (4) for the major occupied site.
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spelling pubmed-32389292011-12-23 6-Bromo-2-[(E)-thio­phen-2-yl­methyl­idene]-2,3,4,9-tetra­hydro-1H-carbazol-1-one Velmurugan, R. Sekar, M. Vijayasankar, A. V. Ramesh, P. Ponnuswamy, M. N. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(12)BrNOS, the cyclo­hexene ring deviates only slightly from planarity (r.m.s. deviation for non-H atoms = 0.047 Å). In the crystal, the mol­ecules are linked into centro­symmetric R (2) (2)(10) dimers via pairs of N—H⋯O hydrogen bonds. The thio­phene ring is disordered over two positions rotated by 180° and with a site-occupation factor of 0.843 (4) for the major occupied site. International Union of Crystallography 2011-11-12 /pmc/articles/PMC3238929/ /pubmed/22199778 http://dx.doi.org/10.1107/S1600536811046551 Text en © Velmurugan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Velmurugan, R.
Sekar, M.
Vijayasankar, A. V.
Ramesh, P.
Ponnuswamy, M. N.
6-Bromo-2-[(E)-thio­phen-2-yl­methyl­idene]-2,3,4,9-tetra­hydro-1H-carbazol-1-one
title 6-Bromo-2-[(E)-thio­phen-2-yl­methyl­idene]-2,3,4,9-tetra­hydro-1H-carbazol-1-one
title_full 6-Bromo-2-[(E)-thio­phen-2-yl­methyl­idene]-2,3,4,9-tetra­hydro-1H-carbazol-1-one
title_fullStr 6-Bromo-2-[(E)-thio­phen-2-yl­methyl­idene]-2,3,4,9-tetra­hydro-1H-carbazol-1-one
title_full_unstemmed 6-Bromo-2-[(E)-thio­phen-2-yl­methyl­idene]-2,3,4,9-tetra­hydro-1H-carbazol-1-one
title_short 6-Bromo-2-[(E)-thio­phen-2-yl­methyl­idene]-2,3,4,9-tetra­hydro-1H-carbazol-1-one
title_sort 6-bromo-2-[(e)-thio­phen-2-yl­methyl­idene]-2,3,4,9-tetra­hydro-1h-carbazol-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238929/
https://www.ncbi.nlm.nih.gov/pubmed/22199778
http://dx.doi.org/10.1107/S1600536811046551
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