Low-temperature superstructure of [(N,N-diisobutyl­carbamo­yl)meth­yl]oct­yl(phen­yl)phosphine oxide (CMPO)

At 120 K, the title compound, C(24)H(42)NO(2)P, crystallizes in a unit cell with a doubled a parameter compared with the room-temperature structure. There are four mol­ecules in the asymmetric unit, one of which shows extensive disorder in a 0.588 (3):0.412 (3) ratio. In the crystal, numerous C—H⋯O...

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Autores principales: Pojarová, Michaela, Fejfarová, Karla, Makrlík, Emanuel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238930/
https://www.ncbi.nlm.nih.gov/pubmed/22199779
http://dx.doi.org/10.1107/S1600536811046939
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author Pojarová, Michaela
Fejfarová, Karla
Makrlík, Emanuel
author_facet Pojarová, Michaela
Fejfarová, Karla
Makrlík, Emanuel
author_sort Pojarová, Michaela
collection PubMed
description At 120 K, the title compound, C(24)H(42)NO(2)P, crystallizes in a unit cell with a doubled a parameter compared with the room-temperature structure. There are four mol­ecules in the asymmetric unit, one of which shows extensive disorder in a 0.588 (3):0.412 (3) ratio. In the crystal, numerous C—H⋯O inter­actions link the mol­ecules.
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spelling pubmed-32389302011-12-23 Low-temperature superstructure of [(N,N-diisobutyl­carbamo­yl)meth­yl]oct­yl(phen­yl)phosphine oxide (CMPO) Pojarová, Michaela Fejfarová, Karla Makrlík, Emanuel Acta Crystallogr Sect E Struct Rep Online Organic Papers At 120 K, the title compound, C(24)H(42)NO(2)P, crystallizes in a unit cell with a doubled a parameter compared with the room-temperature structure. There are four mol­ecules in the asymmetric unit, one of which shows extensive disorder in a 0.588 (3):0.412 (3) ratio. In the crystal, numerous C—H⋯O inter­actions link the mol­ecules. International Union of Crystallography 2011-11-12 /pmc/articles/PMC3238930/ /pubmed/22199779 http://dx.doi.org/10.1107/S1600536811046939 Text en © Pojarová et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pojarová, Michaela
Fejfarová, Karla
Makrlík, Emanuel
Low-temperature superstructure of [(N,N-diisobutyl­carbamo­yl)meth­yl]oct­yl(phen­yl)phosphine oxide (CMPO)
title Low-temperature superstructure of [(N,N-diisobutyl­carbamo­yl)meth­yl]oct­yl(phen­yl)phosphine oxide (CMPO)
title_full Low-temperature superstructure of [(N,N-diisobutyl­carbamo­yl)meth­yl]oct­yl(phen­yl)phosphine oxide (CMPO)
title_fullStr Low-temperature superstructure of [(N,N-diisobutyl­carbamo­yl)meth­yl]oct­yl(phen­yl)phosphine oxide (CMPO)
title_full_unstemmed Low-temperature superstructure of [(N,N-diisobutyl­carbamo­yl)meth­yl]oct­yl(phen­yl)phosphine oxide (CMPO)
title_short Low-temperature superstructure of [(N,N-diisobutyl­carbamo­yl)meth­yl]oct­yl(phen­yl)phosphine oxide (CMPO)
title_sort low-temperature superstructure of [(n,n-diisobutyl­carbamo­yl)meth­yl]oct­yl(phen­yl)phosphine oxide (cmpo)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238930/
https://www.ncbi.nlm.nih.gov/pubmed/22199779
http://dx.doi.org/10.1107/S1600536811046939
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