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7′-(4-Bromophenyl)-5′,6′,7′,7a’-tetrahydrodispiro[indan-2,5′-pyrrolo[1,2-c][1,3]thiazole-6′,2′′-indan]-1,3,1′′-trione
In the title compound, C(28)H(20)BrNO(3)S, the thiazolidine, pyrrolidine and two five-membered carbocyclic rings are in envelope conformations. The bromo-bound phenyl ring forms dihedral angles of 61.97 (18) and 88.30 (17)° with the other two benzene rings. The two benzene rings form a dihedral ang...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238931/ https://www.ncbi.nlm.nih.gov/pubmed/22199780 http://dx.doi.org/10.1107/S1600536811046514 |
| _version_ | 1782219086428635136 |
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| author | Wei, Ang Chee Ali, Mohamed Ashraf Yoon, Yeong Keng Quah, Ching Kheng Fun, Hoong-Kun |
| author_facet | Wei, Ang Chee Ali, Mohamed Ashraf Yoon, Yeong Keng Quah, Ching Kheng Fun, Hoong-Kun |
| author_sort | Wei, Ang Chee |
| collection | PubMed |
| description | In the title compound, C(28)H(20)BrNO(3)S, the thiazolidine, pyrrolidine and two five-membered carbocyclic rings are in envelope conformations. The bromo-bound phenyl ring forms dihedral angles of 61.97 (18) and 88.30 (17)° with the other two benzene rings. The two benzene rings form a dihedral angle of 30.3 (2)°. The molecular structure features an intramolecular C—H⋯O hydrogen bond, which generates an S(6) ring motif. In the crystal, molecules are linked into inversion dimers by pairs of C—H⋯O hydrogen bonds. |
| format | Online Article Text |
| id | pubmed-3238931 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32389312011-12-23 7′-(4-Bromophenyl)-5′,6′,7′,7a’-tetrahydrodispiro[indan-2,5′-pyrrolo[1,2-c][1,3]thiazole-6′,2′′-indan]-1,3,1′′-trione Wei, Ang Chee Ali, Mohamed Ashraf Yoon, Yeong Keng Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(28)H(20)BrNO(3)S, the thiazolidine, pyrrolidine and two five-membered carbocyclic rings are in envelope conformations. The bromo-bound phenyl ring forms dihedral angles of 61.97 (18) and 88.30 (17)° with the other two benzene rings. The two benzene rings form a dihedral angle of 30.3 (2)°. The molecular structure features an intramolecular C—H⋯O hydrogen bond, which generates an S(6) ring motif. In the crystal, molecules are linked into inversion dimers by pairs of C—H⋯O hydrogen bonds. International Union of Crystallography 2011-11-12 /pmc/articles/PMC3238931/ /pubmed/22199780 http://dx.doi.org/10.1107/S1600536811046514 Text en © Wei et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Wei, Ang Chee Ali, Mohamed Ashraf Yoon, Yeong Keng Quah, Ching Kheng Fun, Hoong-Kun 7′-(4-Bromophenyl)-5′,6′,7′,7a’-tetrahydrodispiro[indan-2,5′-pyrrolo[1,2-c][1,3]thiazole-6′,2′′-indan]-1,3,1′′-trione |
| title | 7′-(4-Bromophenyl)-5′,6′,7′,7a’-tetrahydrodispiro[indan-2,5′-pyrrolo[1,2-c][1,3]thiazole-6′,2′′-indan]-1,3,1′′-trione |
| title_full | 7′-(4-Bromophenyl)-5′,6′,7′,7a’-tetrahydrodispiro[indan-2,5′-pyrrolo[1,2-c][1,3]thiazole-6′,2′′-indan]-1,3,1′′-trione |
| title_fullStr | 7′-(4-Bromophenyl)-5′,6′,7′,7a’-tetrahydrodispiro[indan-2,5′-pyrrolo[1,2-c][1,3]thiazole-6′,2′′-indan]-1,3,1′′-trione |
| title_full_unstemmed | 7′-(4-Bromophenyl)-5′,6′,7′,7a’-tetrahydrodispiro[indan-2,5′-pyrrolo[1,2-c][1,3]thiazole-6′,2′′-indan]-1,3,1′′-trione |
| title_short | 7′-(4-Bromophenyl)-5′,6′,7′,7a’-tetrahydrodispiro[indan-2,5′-pyrrolo[1,2-c][1,3]thiazole-6′,2′′-indan]-1,3,1′′-trione |
| title_sort | 7′-(4-bromophenyl)-5′,6′,7′,7a’-tetrahydrodispiro[indan-2,5′-pyrrolo[1,2-c][1,3]thiazole-6′,2′′-indan]-1,3,1′′-trione |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238931/ https://www.ncbi.nlm.nih.gov/pubmed/22199780 http://dx.doi.org/10.1107/S1600536811046514 |
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